Publications

(1) Yartys, V. A.; Akiba, E.; Bowman, R. C., Jr.; Buckley, C. E.; Graetz, J.; Hirscher, M.; Paskevicius, M.; Zhu, M.; Gennett, T.; Autrey, T.; Stavila, V. Metal hydrides: a historical perspective. Journal of Alloys and Compounds 2026, 1050. DOI: 10.1016/j.jallcom.2025.185734.

(2) Way, L.; Charbonnier, V.; Fadonougbo, J. O.; Clulow, R.; Lei, L.; Ling, S. L.; Grant, D.; Dornheim, M.; Banerjee, T.; Breunig, H.; Zlotea, C.; Rowberg, A. J. E.; Guan, P. W.; Stavila, V.; Allendorf, M. D.; Sahlberg, M.; Sakaki, K.; Bartelt, N. C.; Witman, M. D. Efficiently predicting pressure-composition-temperature diagrams to discover low-stability metal hydrides. Journal of Materials Chemistry A 2026, 14 (5), 2967-2976. DOI: 10.1039/d5ta06645j.

(3) Tarancon, A.; Botros, M.; Gangwar, B. P.; Biswas, K.; Divilov, S.; Eckert, H.; Friedrich, R.; Calzolari, A.; Curtarolo, S.; Ludwig, A.; Strauss, F.; Brezesinski, T.; Breitung, B.; Fichtner, M.; He, R.; Cabot, A.; Dąbrowa, J.; Ren, J.-T.; Yuan, Z.-Y.; Zlotea, C.; et al. 2026 Roadmap on compositionally complex and high entropy materials for energy applications. Journal of Physics: Energy 2026, DOI:10.1088/2515-7655/ae57d9.

(4) Rahmouni, M. E.; Agafonov, A.; Greaves, F.; Pineda-Romero, N.; Witman, M. D.; Stavila, V.; Zlotea, C. Enhancing Room-Temperature Hydrogen Storage Properties in Ti-V-Cr-Nb-Mo/Fe Multielement Alloys via Substitutional Tuning. Acs Omega 2026, 11 (10), 16414-16421. DOI: 10.1021/acsomega.5c12329.

(5) Gaykwad, B.; Robinson, D. A.; Humphrey, N.; Wenzel, S. F.; Hui, C.; McCoy, N. A.; El Gabaly, F.; Sugar, J. D.; Witman, M. D.; Jasuja, K.; Ren, H.; Stavila, V. Composition-dependent hydrogen oxidation activity of Pt-Cu nanoparticles prepared using boron-rich nanosheets. Chemical Communications 2026, DOI: 10.1039/D6CC00243A.

(6) Charbonnier, V.; Witman, M. D.; Shinzato, K.; Kim, H.; Koh, J.; Cho, H.; Allendorf, M. D.; Asano, K.; Cho, E. S.; Sakaki, K.; Stavila, V. Performance assessment of AB2 alloys (A = Zr, Ti; B = Mn, Ni, Cr, V, Fe, Al) for hydrogen storage and separation in the presence of carbon dioxide. Journal of Alloys and Compounds 2026, 1055. DOI: 10.1016/j.jallcom.2026.186349.

(7) Bustos, J.; Colliard, I.; Stavila, V.; Kaseman, D. C.; Colla, C. A.; Nyman, M.; Deblonde, G. J. P. Structural and Spectroscopic Characterization of Plutonium and Other Tetravalent Metals Complexed to a Keggin Ion. Inorganic Chemistry 2026, 65 (5), 2705-2716. DOI: 10.1021/acs.inorgchem.5c03627.

(8) Bandaranayake, S.; Schrader, P.; Chen, G. Z.; Tan, L. Z.; Shivanna, M.; Stavila, V.; Luna, J. R.; Ramasesha, K. Phonon-mediated ultrafast dynamics in self-assembled monolayers of 4-mercaptobenzoic acid on gold. Physical Chemistry Chemical Physics 2026. DOI: 10.1039/d5cp04826e.

(9) Witman, M. D.; Davis, B. C.; Stavila, V.; Johnson, T. System and Machine Learning-Guided Materials Design for High-Pressure Hydrogen Compression. Acs Applied Energy Materials 2025, 8 (14), 10140-10148. DOI: 10.1021/acsaem.5c00887.

(10) Wang, X. Y.; Peng, P.; Witman, M. D.; Stavila, V.; Allendorf, M. D.; Breunig, H. M. Technoeconomic Insights into Metal Hydrides for Stationary Hydrogen Storage. Advanced Science 2025, 12 (21). DOI: 10.1002/advs.202415736.

(11) Taylor, W. V.; Klebanoff, L. E.; Ray, K. G.; Li, S. C.; Zhuo, Z. Q.; Kim, M. J.; Dun, C. C.; Johnson, A. C.; Marple, M. A. T.; El Gabaly, F.; Urban, J. J.; Guo, J. H.; Wood, B. C.; Stavila, V.; Allendorf, M. D. Decoding the Desorption Mechanism of 2LiH:1Mg(NH2)2 Using Metal Borohydrides. Acs Applied Energy Materials 2025, 8 (14), 10379-10391. DOI: 10.1021/acsaem.5c01297.

(12) Sugai, C.; Bradley, J. P.; Ishii, H. A.; Davis, B. C.; Yoshida, W. Y.; Stavila, V.; Jensen, C. M. Observation of giant 3D graphenic vesicles encapsulating hydrogen. Journal of Materials Chemistry A 2025, 13 (47). DOI: 10.1039/d5ta06250k.

(13) Shivanna, M.; Torquato, N. A.; Li, S. C.; Marple, M. A. T.; Sugar, J. D.; Foster, M. E.; Berry, A.; Taylor, W. V.; Strange, N. A.; Wang, X. L.; El Gabaly, F.; Chang, T. Y.; Chen, Y. S.; Sharma, P. A.; Lemmon, J.; Sadtler, B.; Wood, B. C.; Allendorf, M. D.; Stavila, V. Single-Electron Transfer Stabilizes Metastable Alane in a Bipyridine-Functionalized MOF Nanopore. Journal of the American Chemical Society 2025, 147 (51), 47398-47408. DOI: 10.1021/jacs.5c15894.

(14) Severa, G.; Wang, L.; Kim, S.; Leick, N.; Kelly, C.; Sugai, C.; Snider, J. L.; Norman, A. G.; Dera, P.; Kotsol, I.; Gennett, T.; Stavila, V.; Jensen, C. M. Graphene Activated Magnesium Diboride for Moderate Pressure and Temperature Hydrogenation to Magnesium Borohydride. Acs Applied Energy Materials 2025, 8 (2), 853-860. DOI: 10.1021/acsaem.4c02302.

(15) Robinson, D. A.; Hood, R.; Peters, N. J.; Kolasinski, R. D.; Brockman, J. D.; Thürmer, K.; Hattar, K.; Lang, E.; Stavila, V.; Cowgill, D. F.; Karnesky, R. A. In situ observation of irradiation-induced enhancement to the desorption pressure of zirconium hydride in a nuclear reactor. Journal of Nuclear Materials 2025, 614. DOI: 10.1016/j.jnucmat.2025.155894.

(16) Nagle-Cocco, L. A. V.; Schneemann, A.; Stone, K. H.; Stavila, V.; Gennett, T.; Strange, N. A. Orientational Disorder of NH3 in Hexammine Magnesium Borohydride. Inorganic Chemistry 2025, 64 (36), 18245-18253. DOI: 10.1021/acs.inorgchem.5c02474.

(17) Kim, S.; Sugai, C.; Hauback, B. C.; Fjellvåg, O. S.; Bradley, J. P.; Ishii, H. A.; Stavila, V.; Jensen, C. M. Enhanced hydrogenation kinetics of magnesium diboride through carbon substitution into the boride layers. Journal of Materials Chemistry A 2025, 13 (48), 41896-41902. DOI: 10.1039/d5ta07495a.

(18) Ji, K.; Banerjee, T.; Witman, M. D.; Allendorf, M. D.; Stavila, V.; Singh, P. Design of lightweight BCC multi-principal element alloys with enhanced hydrogen storage using a machine learning-driven genetic algorithm. Journal of Materials Chemistry A 2025, 13 (47), 41274-41289. DOI: 10.1039/d5ta06903c.

(19) Garelli, F.; Dematteis, E. M.; Stavila, V.; Di Florio, G.; Carbone, C.; Agostini, A.; Palumbo, M.; Baricco, M.; Rizzi, P. Kinetics tuning of TiFe alloys by elemental substitution: Enabling activation under moderate conditions. International Journal of Hydrogen Energy 2025, 162. DOI: 10.1016/j.ijhydene.2025.150720.

(20) Colliard, I.; Stavila, V.; Deblonde, G. J. P. Isolation of a new polyoxometalate complex of plutonium. Chemical Communications 2025, 61 (63), 11858-11861. DOI: 10.1039/d5cc03481g.

(21) Cho, Y.; Witman, M. D.; Park, H. K.; Ko, W. S.; Wood, B. C.; Stavila, V.; Cho, E. S. Data-driven multi-element substitution of TiFe alloys for tunable thermodynamics and enhanced activation behaviour for hydrogen storage. Journal of Materials Chemistry A 2025, 13 (41). DOI: 10.1039/d5ta04389a.

(22) Beltrame, G.; Dematteis, E. M.; Stavila, V.; Rizzi, P.; Baricco, M.; Palumbo, M. Application of Machine Learning and Data Augmentation Algorithms in the Discovery of Metal Hydrides for Hydrogen Storage. Metals 2025, 15 (11). DOI: 10.3390/met15111221.

(23) Bashiri, R.; Lawson, P. S.; He, S.; Nanayakkara, S.; Kim, K.; Barnett, N. S.; Stavila, V.; El Gabaly, F.; Lee, J.; Ayars, E.; So, M. C. Discovery of Dual Ion-Electron Conductivity of Metal-Organic Frameworks via Machine Learning-Guided Experimentation. Chemistry of Materials 2025, 37 (3), 1143-1153. DOI: 10.1021/acs.chemmater.4c02974.

(24) Agafonov, A.; Pineda-Romero, N.; Witman, M. D.; Enblom, V.; Sahlberg, M.; Nassif, V.; Lei, L.; Grant, D. M.; Dornheim, M.; Ling, S. L.; Stavila, V.; Zlotea, C. Promising Alloys for Hydrogen Storage in the Compositional Space of (TiVNb)100-x (Cr,Mo) x High-Entropy Alloys. Acs Applied Materials & Interfaces 2025, 17 (29), 41991-42003. DOI: 10.1021/acsami.5c08574.

(25) Witman, M. D.; Brooks, K. P.; Sprik, S. J.; Wood, B. C.; Heo, T. W.; Ray, K. G.; Klebanoff, L. E.; Acosta, A.; Stavila, V.; Allendorf, M. D. A Bulk versus Nanoscale Hydrogen Storage Paradox Revealed by Material-System Co-Design. Advanced Functional Materials 2024, 34 (48). DOI: 10.1002/adfm.202411763.

(26) Witman, M. D.; Bartelt, N. C.; Ling, S. L.; Guan, P. W.; Way, L.; Allendorf, M. D.; Stavila, V. Phase Diagrams of Alloys and Their Hydrides via On-Lattice Graph Neural Networks and Limited Training Data. Journal of Physical Chemistry Letters 2024, 15 (5), 1500-1506. DOI: 10.1021/acs.jpclett.3c03369.

(27) Shivanna, M.; Elmslie, T. A.; Spataru, C. D.; Duwal, S.; Porcellino, N.; Mouzaya, S.; Pakhanyan, C. P.; El Gabaly, F.; Kawaguchi-Imada, S.; Guo, J. H.; Zhuo, Z. Q.; Kim, M. J.; Sturtevant, B. T.; Teprovich, J. A.; Allendorf, M. D.; Sharma, P. A.; Stavila, V. Nanoconfinement of High Hydrogen-to-Metal Ratio Lanthanum Hydrides in Functionalized Carbon Hosts. Acs Applied Energy Materials 2024, 8 (1), 7-15. DOI: 10.1021/acsaem.4c02100.

(28) Porcellino, N.; Pakhanyan, C.; Elmslie, T.; Shivanna, M.; Duwal, S.; Spataru, C. D.; Lindvall, R.; Somayazulu, M.; Ward, P. A.; Kawaguchi, S. I.; Stavila, V.; Sharma, P. A.; Teprovich, J. A. Pressure-Dependent Phase Behavior of Chemically Synthesized Ytterbium Hydride Nanoparticles and Confinement in CMK-3. Acs Applied Energy Materials 2024, 7 (21), 9608-9615. DOI: 10.1021/acsaem.4c01673.

(29) Lefcochilos-Fogelquist, H. M.; Wan, L. F.; Rowberg, A. J. E.; Kang, S.; Stavila, V.; Klebanoff, L. E.; Allendorf, M. D.; Wood, B. C. Understanding electronic structure tunability by metal dopants for promoting MgB2 hydrogenation. Journal of Applied Physics 2024, 135 (2). DOI: 10.1063/5.0175546.

(30) Lefcochilos-Fogelquist, H. M.; Wan, L. F.; Rowberg, A. J. E.; Kang, S.; Ray, K. G.; Stavila, V.; Klebanoff, L. E.; Allendorf, M. D.; Wood, B. C. Understanding electronic structure tunability by metal dopants for promoting MgB2 hydrogenation ( vol 135, 025003,2024). Journal of Applied Physics 2024, 135 (6). DOI: 10.1063/5.0200282.

(31) Angel, S. M.; Barnett, N. S.; Talin, A. A.; Foster, M. E.; Stavila, V.; Allendorf, M. D.; So, M. C. From insulator to semiconductor: effect of host-guest interactions on charge transport in M-MOF-74 metal-organic frameworks. Journal of Materials Chemistry C 2024, 12 (8). DOI: 10.1039/d3tc04155g.

(32) Agafonov, A.; Pineda-Romero, N.; Witman, M.; Nassif, V.; Vaughan, G. B. M.; Lei, L.; Ling, S. L.; Dornheim, M.; Allendorf, M.; Stavila, V.; Zlotea, C. Destabilizing high-capacity high entropy hydrides via earth abundant substitutions: From predictions to experimental validation. Acta Materialia 2024, 276. DOI: 10.1016/j.actamat.2024.120086.

(33) Witman, M. D.; Ling, S. L.; Wadge, M.; Bouzidi, A.; Pineda-Romero, N.; Clulow, R.; Ek, G.; Chames, J. M.; Allendorf, E. J.; Agarwal, S.; Allendorf, M. D.; Walker, G. S.; Grant, D. M.; Sahlberg, M.; Zlotea, C.; Stavila, V. Towards Pareto optimal high entropy hydrides via data-driven materials discovery. Journal of Materials Chemistry A 2023, 11 (29), 15878-15888. DOI: 10.1039/d3ta02323k.

(34) Strozi, R. B.; Witman, M.; Stavila, V.; Cizek, J.; Sakaki, K.; Kim, H.; Melikhova, O.; Perrière, L.; Machida, A.; Nakahira, Y.; Zepon, G.; Botta, W. J.; Zlotea, C. Elucidating Primary Degradation Mechanisms in High-Cycling-Capacity, Compositionally Tunable High-Entropy Hydrides. Acs Applied Materials & Interfaces 2023, 15 (32), 38412-38422. DOI: 10.1021/acsami.3c05206.

(35) Shivanna, M.; Zheng, J. J.; Ray, K. G.; Lto, S.; Ashitani, H.; Kubota, Y.; Kawaguchi, S.; Stavila, V.; Yao, M. S.; Fujikawa, T.; Otake, K.; Kitagawa, S. Selective sorption of oxygen and nitrous oxide by an electron donor-incorporated flexible coordination network. Communications Chemistry 2023, 6 (1). DOI: 10.1038/s42004-023-00853-1.

(36) Romero, N. P.; Witman, M.; Harvey, K.; Stavila, V.; Nassif, V.; Elkaïm, E.; Zlotea, C. Large Destabilization of (TiVNb)-Based Hydrides via (Al, Mo) Addition: Insights from Experiments and Data-Driven Models. Acs Applied Energy Materials 2023, 6 (24), 12560-12572. DOI: 10.1021/acsaem.3c02696.

(37) Robinson, D. A.; Foster, M. E.; Bennett, C. H.; Bhandarkar, A.; Webster, E. R.; Celebi, A.; Celebi, N.; Fuller, E. J.; Stavila, V.; Spataru, C. D.; Ashby, D. S.; Marinella, M. J.; Krishnakumar, R.; Allendorf, M. D.; Talin, A. A. Tunable Intervalence Charge Transfer in Ruthenium Prussian Blue Analog Enables Stable and Efficient Biocompatible Artificial Synapses. Advanced Materials 2023, 35 (37). DOI: 10.1002/adma.202207595.

(38) Lu, G. M.; Witman, M.; Agarwal, S.; Stavila, V.; Trinkle, D. R. Explainable machine learning for hydrogen diffusion in metals and random binary alloys. Physical Review Materials 2023, 7 (10). DOI: 10.1103/PhysRevMaterials.7.105402.

(39) Hellman, A. N.; Torquato, N. A.; Foster, M. E.; Dun, C.; Reynolds, J. E., III; Yu, C. J.; Tran, A. D.; Shivanna, M.; Garcia, G. F. H.; Yang, J.; Chen, Y.; Su, J.; Urban, J. J.; Allendorf, M. D.; Stavila, V. Heterogenization of Homogeneous Ruthenium(II) Catalysts for Carbon-Neutral Dehydrogenation of Polyalcohols. Acs Applied Energy Materials 2023, 6 (14), 7353-7362. DOI: 10.1021/acsaem.3c00462.

(40) Gunda, H.; Ray, K. G.; Klebanoff, L. E.; Dun, C.; Marple, M. A. T.; Li, S. C.; Sharma, P.; Friddle, R. W.; Sugar, J. D.; Snider, J. L.; Horton, R. D.; Davis, B. C.; Chames, J. M.; Liu, Y. S.; Guo, J. H.; Mason, H. E.; Urban, J. J.; Wood, B. C.; Allendorf, M. D.; Jasuja, K.; Stavila, V. Hydrogen Storage in Partially Exfoliated Magnesium Diboride Multilayers. Small 2023, 19 (6). DOI: 10.1002/smll.202205487.

(41) Dun, C.; Li, S. C.; Chen, L. F.; Horton, R. D.; Allendorf, M. D.; Wood, B. C.; Stavila, V.; Urban, J. J. A Nanoscale Ternary Amide-rGO Composite with Boosted Kinetics for Reversible H2 Storage. Advanced Materials Interfaces 2023, 10 (27). DOI: 10.1002/admi.202300310.

(42) Abou Taka, A.; Reynolds, J. E.; Cole-Filipiak, N. C.; Shivanna, M.; Yu, C. J.; Feng, P. T.; Allendorf, M. D.; Ramasesha, K.; Stavila, V.; McCaslin, L. M. Comparing the structures and photophysical properties of two charge transfer co-crystals. Physical Chemistry Chemical Physics 2023, 25 (40), 27065-27074. DOI: 10.1039/d3cp03720g.

(43) Yoon, S.; Talin, A.; Stavila, V.; Mroz, A. M.; Bennett, T. D.; He, Y. P.; Keen, D. A.; Hendon, C. H.; Allendorf, M. D.; So, M. C. From n- to p-Type Material: Effect of Metal Ion on Charge Transport in Metal-Organic Materials (vol 13, pg 52055, 2021). Acs Applied Materials & Interfaces 2022, 14 (16), 19079-19079. DOI: 10.1021/acsami.2c05799.

(44) Strange, N. A.; Leick, N.; Shulda, S.; Schneemann, A.; Stavila, V.; Lipton, A. S.; Toney, M. F.; Gennett, T.; Christensen, S. T. Reactive Vapor-Phase Additives toward Destabilizing γ-Mg(BH4)2 for Improved Hydrogen Release. Acs Applied Energy Materials 2022, 5 (2), 1690-1700. DOI: 10.1021/acsaem.1c03128.

(45) Strange, N. A.; Leick, N.; Bell, R. T.; Fitzgerald, M. A.; Pylypenko, S.; Schneemann, A.; Stavila, V.; Gennett, T. Thermal Decomposition of Magnesium Borohydride: New Insights from Synchrotron X-ray Scattering. Chemistry of Materials 2022, 34 (24), 10940-10951. DOI: 10.1021/acs.chemmater.2c02925.

(46) Snider, J. L.; Mattox, T. M.; Liu, Y. S.; Wan, L. F.; Wijeratne, P.; Allendorf, M. D.; Stavila; Wood, B. C.; Klebanoff, L. E. The influence of LiH and TiH2 on hydrogen storage in MgB2 I: Promotion of bulk hydrogenation at reduced temperature. International Journal of Hydrogen Energy 2022, 47 (1), 387-402. DOI: 10.1016/j.ijhydene.2021.09.169.

(47) Snider, J. L.; Mattox, T. M.; Liu, Y. S.; Wan, L. F.; Wijeratne, P.; Allendorf, M. D.; Stavila; Wood, B. C.; Klebanoff, L. E. The influence of LiH and TiH2 on hydrogen storage in MgB2 II. XPS study of surface and near-surface phenomena. International Journal of Hydrogen Energy 2022, 47 (1), 403-419. DOI: 10.1016/j.ijhydene.2021.09.163.

(48) Reynolds, J. E., III; Acosta, A. C.; Kang, S. Y.; Li, S. C.; Lipton, A. S.; Bowden, M. E.; Myllenbeck, N. R.; Schneemann, A.; Leick, N.; Bhandarkar, A.; Reed, C.; Horton, R. D.; Gennett, T.; Wood, B. C.; Allendorf, M. D.; Stavila, V. Teaching an Old Reagent New Tricks: Synthesis, Unusual Reactivity, and Solution Dynamics of Borohydride Grignard Compounds. Organometallics 2022, 41 (20), 2823-2832. DOI: 10.1021/acs.organomet.2c00284.

(49) Ray, K. G.; Klebano, L. E.; Stavila, V.; Kang, S. Y.; Wan, L. W. F.; Li, S. C.; Heo, T. W.; Allendorf, M. D.; Lee, J. R. I.; Baker, A. A.; Wood, B. C. Understanding Hydrogenation Chemistry at MgB2 Reactive Edges from Ab Initio Molecular Dynamics. Acs Applied Materials & Interfaces 2022, 14 (18), 20430-20442. DOI: 10.1021/acsami.1c23524.

(50) Pineda-Romero, N.; Witman, M.; Stavila, V.; Zlotea, C. The effect of 10 at.% Al addition on the hydrogen storage properties of the Ti0.33V0.33Nb0.33 multi-principal element alloy. Intermetallics 2022, 146. DOI: 10.1016/j.intermet.2022.107590.

(51) Pimienta, J. A. P.; Papa, G.; Sun, J.; Stavila, V.; Sanchez, A.; Gladden, J. M.; Simmons, B. A. One-pot ethanol production under optimized pretreatment conditions using agave bagasse at high solids loading with low-cost biocompatible protic ionic liquid. Green Chemistry 2022, 24 (1), 207-217. DOI: 10.1039/d1gc03774a.

(52) Osterrieth, J. W. M.; Rampersad, J.; Madden, D.; Rampal, N.; Skoric, L.; Connolly, B.; Allendorf, M. D.; Stavila, V.; Snider, J. L.; Ameloot, R.; Marreiros, J.; Ania, C.; Azevedo, D.; Vilarrasa-Garcia, E.; Santos, B. F.; Bu, X. H.; Chang, Z.; Bunzen, H.; Champness, N. R.; Griffin, S. L.; et al. How Reproducible are Surface Areas Calculated from the BET Equation? Advanced Materials 2022, 34 (27). DOI: 10.1002/adma.202201502.

(53) Madden, D. G.; O’Nolan, D.; Rampal, N.; Babu, R.; Camur, C.; Al Shakhs, A. N.; Zhang, S. Y.; Rance, G. A.; Perez, J.; Casati, N. P. M.; Cuadrado-Collados, C.; O’Sullivan, D.; Rice, N. P.; Gennett, T.; Parilla, P.; Shulda, S.; Hurst, K. E.; Stavila, V.; Allendorf, M. D.; Silvestre-Albero, J.; et al. Densified HKUST-1 Monoliths as a Route to High Volumetric and Gravimetric Hydrogen Storage Capacity. Journal of the American Chemical Society 2022, 144 (30), 13729-13739. DOI: 10.1021/jacs.2c04608.

(54) Green, M.; Kaydanik, K.; Orozco, M.; Hanna, L.; Marple, M. A. T.; Fessler, K. A. S.; Jones, W. B.; Stavila, V.; Ward, P. A.; Teprovich, J. A. Closo-Borate Gel Polymer Electrolyte with Remarkable Electrochemical Stability and a Wide Operating Temperature Window. Advanced Science 2022, 9 (16). DOI: 10.1002/advs.202106032.

(55) Fitzgerald, M.; Shulda, S.; Strange, N. A.; Schneemann, A.; Stavila, V.; Wan, L. F.; Gross, K.; Gennett, T.; Christensen, S.; Pylypenko, S.; Leick, N. Low-Temperature Dehydrogenation of Vapor-Deposited Magnesium Borohydrides Imaged Using Identical Location Microscopy. Journal of Physical Chemistry C 2022, 126 (45), 19024-19034. DOI: 10.1021/acs.jpcc.2c04777.

(56) Dun, C.; Jeong, S.; Kwon, D. H.; Kang, S.; Stavila, V.; Zhang, Z. L.; Lee, J. W.; Mattox, T. M.; Heo, T. W.; Wood, B. C.; Urban, J. J. Hydrogen Storage Performance of Preferentially Oriented Mg/rGO Hybrids. Chemistry of Materials 2022, 34 (7), 2963-2971. DOI: 10.1021/acs.chemmater.1c03714.

(57) Chen, L. N.; Verma, P.; Hou, K. P.; Qi, Z. Y.; Zhang, S. C.; Liu, Y. S.; Guo, J. H.; Stavila, V.; Allendorf, M. D.; Zheng, L. S.; Salmeron, M.; Prendergast, D.; Somorjai, G. A.; Su, J. Reversible dehydrogenation and rehydrogenation of cyclohexane and methylcyclohexane by single-site platinum catalyst. Nature Communications 2022, 13 (1). DOI: 10.1038/s41467-022-28607-y.

(58) Allendorf, M. D.; Stavila, V.; Snider, J. L.; Witman, M.; Bowden, M. E.; Brooks, K.; Tran, B. L.; Autrey, T. Challenges to developing materials for the transport and storage of hydrogen. Nature Chemistry 2022, 14 (11), 1214-+. DOI: 10.1038/s41557-022-01056-2.

(59) Yoon, S.; Talin, A. A.; Stavila, V.; Mroz, A. M.; Bennett, T. D.; He, Y. P.; Keen, D. A.; Hendon, C. H.; Allendorf, M. D.; So, M. C. From n- to p-Type Material: Effect of Metal Ion on Charge Transport in Metal-Organic Materials. Acs Applied Materials & Interfaces 2021, 13 (44), 52055-52062. DOI: 10.1021/acsami.1c09130.

(60) Witman, M.; Ek, G.; Ling, S. L.; Chames, J.; Agarwal, S.; Wong, J.; Allendorf, M. D.; Sahlberg, M.; Stavila, V. Data-Driven Discovery and Synthesis of High Entropy Alloy Hydrides with Targeted Thermodynamic Stability. Chemistry of Materials 2021, 33 (11), 4067-4076. DOI: 10.1021/acs.chemmater.1c00647.

(61) Stavila, V.; Li, S. C.; Dun, C.; Marple, M. A. T.; Mason, H. E.; Snider, J. L.; Reynolds, J. E.; El Gabaly, F.; Sugar, J. D.; Spataru, C. D.; Zhou, X. W.; Dizdar, B.; Majzoub, E. H.; Chatterjee, R.; Yano, J.; Schlomberg, H.; Lotsch, B.; Urban, J. J.; Wood, B. C.; Allendorf, M. D. Defying Thermodynamics: Stabilization of Alane Within Covalent Triazine Frameworks for Reversible Hydrogen Storage. Angewandte Chemie-International Edition 2021, 60 (49), 25815-25824. DOI: 10.1002/anie.202107507.

(62) Snider, J. L.; Su, J.; Verma, P.; El Gabaly, F.; Sugar, J. D.; Chen, L. N.; Chames, J. M.; Talin, A. A.; Dun, C. C.; Urban, J. J.; Stavila, V.; Prendergast, D.; Somorjai, G. A.; Allendorf, M. D. Stabilized open metal sites in bimetallic metal-organic framework catalysts for hydrogen production from alcohols. Journal of Materials Chemistry A 2021, 9 (17), 10869-10881. DOI: 10.1039/d1ta00222h.

(63) Li, S.; Gunda, H.; Ray, K. G.; Wong, C. S.; Xiao, P. H.; Friddle, R. W.; Liu, Y. S.; Kang, S. Y.; Dun, C.; Sugar, J. D.; Kolasinski, R. D.; Wan, L. F.; Baker, A. A.; Lee, J. R. I.; Urban, J. J.; Jasuja, K.; Allendorf, M. D.; Stavila, V.; Wood, B. C. Spontaneous dynamical disordering of borophenes in MgB2 and related metal borides. Nature Communications 2021, 12 (1). DOI: 10.1038/s41467-021-26512-4.

(64) Leick, N.; Strange, N. A.; Schneemann, A.; Stavila, V.; Gross, K.; Washton, N.; Settle, A.; Martinez, M. B.; Gennett, T.; Christensen, S. T. Al2O3 Atomic Layer Deposition on Nanostructured γ-Mg(BH4)2 for H2 Storage. Acs Applied Energy Materials 2021, 4 (2), 1150-1162. DOI: 10.1021/acsaem.0c02314.

(65) Jayaramulu, K.; Horn, M.; Schneemann, A.; Saini, H.; Bakandritsos, A.; Ranc, V.; Petr, M.; Stavila, V.; Narayana, C.; Scheibe, B.; Kment, S.; Otyepka, M.; Motta, N.; Dubal, D.; Zboril, R.; Fischer, R. A. Covalent Graphene-MOF Hybrids for High-Performance Asymmetric Supercapacitors. Advanced Materials 2021, 33 (4). DOI: 10.1002/adma.202004560.

(66) Gunda, H.; Klebanoff, L. E.; Sharma, P. A.; Varma, A. K.; Dolia, V.; Jasuja, K.; Stavila, V. Progress, Challenges, and Opportunities in the Synthesis, Characterization, and Application of Metal-Boride-Derived Two-Dimensional Nanostructures. Acs Materials Letters 2021, 3 (5), 535-556. DOI: 10.1021/acsmaterialslett.1c00086.

(67) Ek, G.; Nygård, M. M.; Pavan, A. F.; Montero, J.; Henry, P. F.; Sorby, M. H.; Witman, M.; Stavila, V.; Zlotea, C.; Hauback, B. C.; Sahlberg, M. Elucidating the Effects of the Composition on Hydrogen Sorption in TiVZrNbHf-Based High-Entropy Alloys. Inorganic Chemistry 2021, 60 (2), 1125-1133. DOI: 10.1021/acs.inorgchem.0c03270.

(68) Dun, C.; Jeong, S.; Liu, Y. S.; Leick, N.; Mattox, T. M.; Guo, J. H.; Lee, J. W.; Gennett, T.; Stavila, V.; Urban, J. J. Additive Destabilization of Porous Magnesium Borohydride Framework with Core-Shell Structure. Small 2021, 17 (44). DOI: 10.1002/smll.202101989.

(69) Cho, Y. J.; Li, S. C.; Snider, J. L.; Marple, M. A. T.; Strange, N. A.; Sugar, J. D.; El Gabaly, F.; Schneemann, A.; Kang, S. S.; Kang, M. H.; Park, H.; Park, J.; Wan, L. W. F.; Mason, H. E.; Allendorf, M. D.; Wood, B. C.; Cho, E. S.; Stavila, V. Reversing the Irreversible: Thermodynamic Stabilization of LiAlH4 Nanoconfined Within a Nitrogen-Doped Carbon Host. Acs Nano 2021, 15 (6), 10163-10174. DOI: 10.1021/acsnano.1c02079.

(70) Bell, R. T.; Strange, N. A.; Leick, N.; Stavila, V.; Bowden, M. E.; Autrey, T. S.; Gennett, T. Mg(BH4)2-Based Hybrid Metal-Organic Borohydride System Exhibiting Enhanced Chemical Stability in Melt. Acs Applied Energy Materials 2021, 4 (2), 1704-1713. DOI: 10.1021/acsaem.0c02861.

(71) Andersson, M. S.; Stavila, V.; Skripov, A.; Dimitrievska, M.; Psurek, M. T.; Leao, J. B.; Babanova, O. A.; Skoryunov, R.; Soloninin, A.; Karlsson, M.; Udovic, T. J. Promoting Persistent Superionic Conductivity in Sodium Monocarba-closo-dodecaborate NaCB11H12 via Confinement within Nanoporous Silica. Journal of Physical Chemistry C 2021, 125 (30), 16689-16699. DOI: 10.1021/acs.jpcc.1c03589.

(72) Allendorf, M. D.; Stavila, V.; Witman, M.; Brozek, C. K.; Hendon, C. H. What Lies beneath a Metal-Organic Framework Crystal Structure? New Design Principles from Unexpected Behaviors. Journal of the American Chemical Society 2021, 143 (18), 6705-6723. DOI: 10.1021/jacs.0c10777.

(73) Witman, M.; Ling, S. L.; Stavila, V.; Wijeratne, P.; Furukawa, H.; Allendorf, M. D. Design principles for the ultimate gas deliverable capacity material: nonporous to porous deformations without volume change. Molecular Systems Design & Engineering 2020, 5 (9), 1491-1503. DOI: 10.1039/d0me00122h.

(74) Witman, M.; Ling, S. L.; Grant, D. M.; Walker, G. S.; Agarwal, S.; Stavila, V.; Allendorf, M. D. Extracting an Empirical Intermetallic Hydride Design Principle from Limited Data via Interpretable Machine Learning. Journal of Physical Chemistry Letters 2020, 11 (1), 40-47. DOI: 10.1021/acs.jpclett.9b02971.

(75) White, J. L.; Strange, N. A.; Sugar, J. D.; Snider, J. L.; Schneemann, A.; Lipton, A. S.; Toney, M. F.; Allendorf, M. D.; Stavila, V. Melting of Magnesium Borohydride under High Hydrogen Pressure: Thermodynamic Stability and Effects of Nanoconfinement. Chemistry of Materials 2020, 32 (13), 5604-5615. DOI: 10.1021/acs.chemmater.0c01050.

(76) White, J. L.; Baker, A. A.; Marcus, M. A.; Snider, J. L.; Wang, T. C.; Lee, J. R.; Kilcoyne, D. A. L.; Allendorf, M. D.; Stavila, V.; El Gabaly, F. The Inside-Outs of Metal Hydride Dehydrogenation: Imaging the Phase Evolution of the Li-N-H Hydrogen Storage System. Advanced Materials Interfaces 2020, 7 (7). DOI: 10.1002/admi.201901905.

(77) Spataru, C. D.; Heo, T. W.; Wood, B. C.; Stavila, V.; Kang, S.; Allendorf, M. D.; Zhou, X. W. Statistically averaged molecular dynamics simulations of hydrogen diffusion in magnesium and magnesium hydrides. Physical Review Materials 2020, 4 (10). DOI: 10.1103/PhysRevMaterials.4.105401.

(78) Schneemann, A.; Wan, L. F.; Lipton, A. S.; Liu, Y. S.; Snider, J. L.; Baker, A. A.; Sugar, J. D.; Spataru, C. D.; Guo, J. H.; Autrey, T. S.; Jorgensen, M.; Jensen, T. R.; Wood, B. C.; Allendorf, M. D.; Stavila, V. Nanoconfinement of Molecular Magnesium Borohydride Captured in a Bipyridine-Functionalized Metal-Organic Framework. Acs Nano 2020, 14 (8), 10294-10304. DOI: 10.1021/acsnano.0c03764.

(79) Liu, Y. S.; Ray, K. G.; Jorgensen, M.; Mattox, T. M.; Cowgill, D. F.; Eshelman, H.; Sawvel, A. M.; Snider, J. L.; York, W.; Wijeratne, P.; Pham, A. L.; Gunda, H.; Li, S.; Heo, T. W.; Kang, S.; Jensen, T. R.; Stavila; Wood, B. C.; Klebanoff, L. E. Nanoscale Mg-B via Surfactant Ball Milling of MgB2: Morphology, Composition, and Improved Hydrogen Storage Properties. Journal of Physical Chemistry C 2020, 124 (39), 21761-21771. DOI: 10.1021/acs.jpcc.0c05142.

(80) Jorgensen, M.; Shea, P. T.; Tomich, A. W.; Varley, J. B.; Bercx, M.; Lovera, S.; Cerny, R.; Zhou, W.; Udovic, T. J.; Lavallo, V.; Jensen, T. R.; Wood, B. C.; Stavila, V. Understanding Superionic Conductivity in Lithium and Sodium Salts of Weakly Coordinating Closo-Hexahalocarbaborate Anions. Chemistry of Materials 2020, 32 (4), 1475-1487. DOI: 10.1021/acs.chemmater.9b04383.

(81) Jeong, S.; Heo, T. W.; Oktawiec, J.; Shi, R. P.; Kang, S.; White, J. L.; Schneemann, A.; Zaia, E. W.; Wan, L. W. F.; Ray, K. G.; Liu, Y. S.; Stavila, V.; Guo, J. H.; Long, J. R.; Wood, B. C.; Urban, J. J. A Mechanistic Analysis of Phase Evolution and Hydrogen Storage Behavior in Nanocrystalline Mg(BH4)2 within Reduced Graphene Oxide. Acs Nano 2020, 14 (2), 1745-1756. DOI: 10.1021/acsnano.9b07454.

(82) Harris, Z. D.; Ronevich, J. A.; Stavila, V.; Somerday, B. P. On the fatigue crack growth behavior of Ti-10V-2Fe-3Al in gaseous hydrogen. International Journal of Hydrogen Energy 2020, 45 (51), 27929-27940. DOI: 10.1016/j.ijhydene.2020.07.046.

(83) Dimitrievska, M.; Wu, H.; Stavila, V.; Babanova, O. A.; Skoryunov, R.; Soloninin, A.; Zhou, W.; Trump, B. A.; Andersson, M. S.; Skripov, A.; Udovic, T. J. Structural and Dynamical Properties of Potassium Dodecahydro-monocarba-closo-dodecaborate: KCB11H12. Journal of Physical Chemistry C 2020, 124 (33), 17992-18002. DOI: 10.1021/acs.jpcc.0c05038.

(84) Allendorf, M. D.; Dong, R. H.; Feng, X. L.; Kaskel, S.; Matoga, D.; Stavila, V. Electronic Devices Using Open Framework Materials. Chemical Reviews 2020, 120 (16), 8581-8640. DOI: 10.1021/acs.chemrev.0c00033.

(85) Zhou, X. W.; Kang, S.; Heo, T. W.; Wood, B. C.; Stavila, V.; Allendorf, M. D. An Analytical Bond Order Potential for Mg-H Systems. Chemphyschem 2019, 20 (10), 1404-1411. DOI: 10.1002/cphc.201800991.

(86) White, J. L.; Rowberg, A. J. E.; Wan, L. W. F.; Kang, S.; Ogitsu, T.; Kolasinski, R. D.; Whaley, J. A.; Baker, A. A.; Lee, J. R. I.; Liu, Y. S.; Trotochaud, L.; Guo, J. G.; Stavila, V.; Prendergast, D.; Bluhm, H.; Allendorf, M. D.; Wood, B. C.; El Gabaly, F. Identifying the Role of Dynamic Surface Hydroxides in the Dehydrogenation of Ti-Doped NaAlH4. Acs Applied Materials & Interfaces 2019, 11 (5), 4930-4941. DOI: 10.1021/acsami.8b17650.

(87) Wang, T. C.; White, J. L.; Bie, B. L.; Deng, H. X.; Edgington, J.; Sugar, J. D.; Stavila, V.; Allendorf, M. D. Design Rules for Metal-Organic Framework Stability in High-Pressure Hydrogen Environments. Chemphyschem 2019, 20 (10), 1305-1310. DOI: 10.1002/cphc.201801190.

(88) Wang, T. C.; Doty, F. P.; Benin, A. I.; Sugar, J. D.; York, W. L.; Reinheimer, E. W.; Stavila, V.; Allendorf, M. D. Get the light out: nanoscaling MOFs for luminescence sensing and optical applications. Chemical Communications 2019, 55 (32), 4647-4650. DOI: 10.1039/c9cc01673b.

(89) Sugai, C.; Kim, S.; Severa, G.; White, J. L.; Leick, N.; Martinez, M. B.; Gennett, T.; Stavila, V.; Jensen, C. Kinetic Enhancement of Direct Hydrogenation of MgB2 to Mg(BH4)2 upon Mechanical Milling with THF, MgH2, and/or Mg. Chemphyschem 2019, 20 (10), 1301-1304. DOI: 10.1002/cphc.201801187.

(90) Stavila, V.; Foster, M.; Brown, J. W.; Davis, R. W.; Edgington, J.; Benin, A. I.; Zarkesh, R. A.; Parthasarathi, R.; Hoyt, D. W.; Walter, E. D.; Andersen, A.; Washton, N. M.; Lipton, A. S.; Allendorf, M. D. IRMOF-74(n)-Mg: a novel catalyst series for hydrogen activation and hydrogenolysis of C-O bonds. Chemical Science 2019, 10 (42), 9880-9892. DOI: 10.1039/c9sc01018a.

(91) Pimienta, J. A. P.; Papa, G.; Rodriguez, A.; Barcelos, C. A.; Liang, L.; Stavila, V.; Sanchez, A.; Gladden, J. M.; Simmons, B. A. Pilot- scale hydrothermal pretreatment and optimized saccharification enables bisabolene production from multiple feedstocks. Green Chemistry 2019, 21 (11), 3152-3164. DOI: 10.1039/c9gc00323a.

(92) Nygren, R. E.; Matthews, G. F.; Morgan, T. W.; Silburn, S. A.; Rosenfeld, J. H.; North, M. T.; Tallarigo, A.; Stavila, V. N. Post-test examination of a Li-Ta heat pipe exposed to H plasma in Magnum PSI. Fusion Engineering and Design 2019, 146, 2603-2607. DOI: 10.1016/j.fusengdes.2019.04.053.

(93) Liu, Y. S.; Klebanoff, L. E.; Wijeratne, P.; Cowgill, D. F.; Stavila; Heo, T. W.; Kang, S.; Baker, A. A.; Lee, J. R.; Mattox, T. M.; Ray, K. G.; Sugar, J. D.; Wood, B. C. Investigating possible kinetic limitations to MgB2 hydrogenation. International Journal of Hydrogen Energy 2019, 44 (59), 31239-31256. DOI: 10.1016/j.ijhydene.2019.09.125.

(94) Liu, Y. S.; Jeong, S.; White, J. L.; Feng, X. F.; Cho, E. S.; Stavila, V.; Allendorf, M. D.; Urban, J. J.; Guo, J. H. In-Situ/Operando X-ray Characterization of Metal Hydrides. Chemphyschem 2019, 20 (10), 1261-1271. DOI: 10.1002/cphc.201801185.

(95) Liu, F.; Lane, P.; Hewson, J. C.; Stavila, V.; Tran-Gyamfi, M. B.; Hamel, M.; Lane, T. W.; Davis, R. W. Development of a closed-loop process for fusel alcohol production and nutrient recycling from microalgae biomass. Bioresource Technology 2019, 283, 350-357. DOI: 10.1016/j.biortech.2019.03.006.

(96) Hodgson-Kratky, K.; Papa, G.; Rodriguez, A.; Stavila, V.; Simmons, B.; Botha, F.; Furtado, A.; Henry, R. Relationship between sugarcane culm and leaf biomass composition and saccharification efficiency. Biotechnology for Biofuels 2019, 12 (1). DOI: 10.1186/s13068-019-1588-3.

(97) Crandall, B. S.; Zhang, J. Y.; Stavila, V.; Allendorf, M. D.; Li, Z. L. Desulfurization of Liquid Hydrocarbon Fuels with Microporous and Mesoporous Materials: Metal-Organic Frameworks, Zeolites, and Mesoporous Silicas. Industrial & Engineering Chemistry Research 2019, 58 (42), 19322-19352. DOI: 10.1021/acs.iecr.9b03183.

(98) Chen, L. N.; Hou, K. P.; Liu, Y. S.; Qi, Z. Y.; Zheng, Q.; Lu, Y. H.; Chen, J. Y.; Chen, J. L.; Pao, C. W.; Wang, S. B.; Li, Y. B.; Xie, S. H.; Liu, F. D.; Prendergast, D.; Klebanoff, L. E.; Stavila, V.; Allendorf, M. D.; Guo, J. H.; Zheng, L. S.; Su, J.; Somorjai, G. A. Efficient Hydrogen Production from Methanol Using a Single-Site Pt1/CeO2 Catalyst. Journal of the American Chemical Society 2019, 141 (45), 17995-17999. DOI: 10.1021/jacs.9b09431.

(99) Zhou, X. W.; Heo, T. W.; Wood, B. C.; Stavila, V.; Kang, S.; Allendorf, M. D. Temperature- and concentration-dependent hydrogen diffusivity in palladium from statistically-averaged molecular dynamics simulations. Scripta Materialia 2018, 149, 103-107. DOI: 10.1016/j.scriptamat.2018.02.010.

(100) Zhou, X. W.; Heo, T. W.; Wood, B. C.; Stavila, V.; Kang, S.; Allendorf, M. D. Molecular dynamics studies of fundamental bulk properties of palladium hydrides for hydrogen storage. Journal of Applied Physics 2018, 123 (22). DOI: 10.1063/1.5022190.

(101) Ullman, A. M.; Jones, C. G.; Doty, F. P.; Stavila, V.; Talin, A. A.; Allendorf, M. D. Hybrid Polymer/Metal-Organic Framework Films for Colorimetric Water Sensing over a Wide Concentration Range. Acs Applied Materials & Interfaces 2018, 10 (28), 24201-24208. DOI: 10.1021/acsami.8b07377.

(102) Thürmer, K.; Schneider, C.; Stavila, V.; Friddle, R. W.; Leonard, F.; Fischer, R. A.; Allendorf, M. D.; Talin, A. A. Surface Morphology and Electrical Properties of Cu3BTC2 Thin Films Before and After Reaction with TCNQ. Acs Applied Materials & Interfaces 2018, 10 (45), 39400-39410. DOI: 10.1021/acsami.8b15158.

(103) Skripov, A. V.; Skoryunov, R. V.; Soloninin, A. V.; Babanova, O. A.; Stavila, V.; Udovic, T. J. Nuclear Magnetic Resonance Study of Anion and Cation Reorientational Dynamics in (NH4)2B12H12. Journal of Physical Chemistry C 2018, 122 (6), 3256-3262. DOI: 10.1021/acs.jpcc.7b12046.

(104) Schneemann, A.; White, J. L.; Kang, S.; Jeong, S.; Wan, L. W. F.; Cho, E. S.; Heo, T. W.; Prendergast, D.; Urban, J. J.; Wood, B. C.; Allendorf, M. D.; Stavila, V. Nanostructured Metal Hydrides for Hydrogen Storage. Chemical Reviews 2018, 118 (22), 10775-10839. DOI: 10.1021/acs.chemrev.8b00313.

(105) Melaet, G.; Stavila, V.; Klebanoff, L.; Somorjai, G. A. The effect of aluminum and platinum additives on hydrogen adsorption on mesoporous silicates. Physical Chemistry Chemical Physics 2018, 20 (17), 12075-12083. DOI: 10.1039/c7cp07015b.

(106) Kang, S.; Klebanoff, L. E.; Baker, A. A.; Cowgill, D. F.; Stavila, V.; Lee, J. R. I.; Nielsen, M. H.; Ray, K. G.; Liu, Y. S.; Wood, B. C. Assessing the reactivity of TiCl3 and TiF3 with hydrogen. International Journal of Hydrogen Energy 2018, 43 (31), 14507-14519. DOI: 10.1016/j.ijhydene.2018.05.128.

(107) Jensen, S. R. H.; Paskevicius, M.; Hansen, B. R. S.; Jakobsen, A. S.; Moller, K. T.; White, J. L.; Allendorf, M. D.; Stavila, V.; Skibsted, J.; Jensen, T. R. Hydrogenation properties of lithium and sodium hydride – closo-borate, B10H10 2- and B12H12 2-, composites. Physical Chemistry Chemical Physics 2018, 20 (23), 16266-16275. DOI: 10.1039/c7cp07776a.

(108) Dimitrievska, M.; Stavila, V.; Soloninin, A. V.; Skoryunov, R. V.; Babanova, O. A.; Wu, H.; Zhou, W.; Tang, W. S.; Faraone, A.; Tarver, J. D.; Trump, B. A.; Skripov, A. V.; Udovic, T. J. Nature of Decahydro-closo-decaborate Anion Reorientations in an Ordered Alkali-Metal Salt: Rb2B10H10. Journal of Physical Chemistry C 2018, 122 (27), 15198-15207. DOI: 10.1021/acs.jpcc.8b04385.

(109) Dimitrievska, M.; Shea, P.; Kweon, K. E.; Bercx, M.; Varley, J. B.; Tang, W. S.; Skripov, A. V.; Stavila, V.; Udovic, T. J.; Wood, B. C. Carbon Incorporation and Anion Dynamics as Synergistic Drivers for Ultrafast Diffusion in Superionic LiCB11H12 and NaCB11H12. Advanced Energy Materials 2018, 8 (15). DOI: 10.1002/aenm.201703422.

(110) Carr, C. L.; Jayawardana, W.; Zou, H. Y.; White, J. L.; El Gabaly, F.; Conradi, M. S.; Stavila, V.; Allendorf, M. D.; Majzoub, E. H. Anomalous H2 Desorption Rate of NaAlH4 Confined in Nitrogen-Doped Nanoporous Carbon Frameworks. Chemistry of Materials 2018, 30 (9), 2930-2938. DOI: 10.1021/acs.chemmater.8b00305.

(111) Camp, J.; Stavila, V.; Allendorf, M. D.; Prendergast, D.; Haranczyk, M. Critical Factors in Computational Characterization of Hydrogen Storage in Metal-Organic Frameworks. Journal of Physical Chemistry C 2018, 122 (33), 18957-18967. DOI: 10.1021/acs.jpcc.8b04021.

(112) Allendorf, M. D.; Hulvey, Z.; Gennett, T.; Ahmed, A.; Autrey, T.; Camp, J.; Cho, E. S.; Furukawa, H.; Haranczyk, M.; Head-Gordon, M.; Jeong, S.; Karkamkar, A.; Liu, D. J.; Long, J. R.; Meihaus, K. R.; Nayyar, I. H.; Nazarov, R.; Siegel, D. J.; Stavila, V.; Urban, J. J.; et al. An assessment of strategies for the development of solid-state adsorbents for vehicular hydrogen storage. Energy & Environmental Science 2018, 11 (10), 2784-2812. DOI: 10.1039/c8ee01085d.

(113) Wood, B. C.; Stavila, V.; Poonyayant, N.; Heo, T. W.; Ray, K. G.; Klebanoff, L. E.; Udovic, T. J.; Lee, J. R. I.; Angboonpong, N.; Sugar, J. D.; Pakawatpanurut, P. Nanointerface-Driven Reversible Hydrogen Storage in the Nanoconfined Li-N-H System. Advanced Materials Interfaces 2017, 4 (3). DOI: 10.1002/admi.201600803.

(114) Varley, J. B.; Kweon, K.; Mehta, P.; Shea, P.; Heo, T. W.; Udovic, T. J.; Stavila, V.; Wood, B. C. Understanding Ionic Conductivity Trends in Polyborane Solid Electrolytes from Ab Initio Molecular Dynamics. Acs Energy Letters 2017, 2 (1), 250-255. DOI: 10.1021/acsenergylett.6b00620.

(115) Tang, W. S.; Dimitrievska, M.; Stavila, V.; Zhou, W.; Wu, H.; Talin, A. A.; Udovic, T. J. Order-Disorder Transitions and Superionic Conductivity in the Sodium nido-Undeca(carba)borates. Chemistry of Materials 2017, 29 (24), 10496-10509. DOI: 10.1021/acs.chemmater.7b04332.

(116) Sun, L.; Liao, B. L.; Sheberla, D.; Kraemer, D.; Zhou, J. W.; Stach, E. A.; Zakharov, D.; Stavila, V.; Talin, A. A.; Ge, Y. C.; Allendorf, M. D.; Chen, G.; Léonard, F.; Dinca, M. A Microporous and Naturally Nanostructured Thermoelectric Metal-Organic Framework with Ultralow Thermal Conductivity. Joule 2017, 1 (1), 168-177. DOI: 10.1016/j.joule.2017.07.018.

(117) Stavila, V. Structural properties of metal closo-polyborates and their relevance to energy storage applications. Acta Crystallographica a-Foundation and Advances 2017, 73, A263-A263. DOI: 10.1107/s0108767317097410.

(118) Spoerke, E. D.; Small, L. J.; Foster, M. E.; Wheeler, J.; Ullman, A. M.; Stavila, V.; Rodriguez, M.; Allendorf, M. D. MOF-Sensitized Solar Cells Enabled by a Pillared Porphyrin Framework. Journal of Physical Chemistry C 2017, 121 (9), 4816-4824. DOI: 10.1021/acs.jpcc.6b11251.

(119) Soloninin, A. V.; Dimitrievska, M.; Skoryunov, R. V.; Babanova, O. A.; Skripov, A. V.; Tang, W. S.; Stavila, V.; Orimo, S.; Udovic, T. J. Comparison of Anion Reorientational Dynamics in MCB9Hi10 and M2B10H10 (M = Li, Na) via Nuclear Magnetic Resonance and Quasielastic Neutron Scattering Studies. Journal of Physical Chemistry C 2017, 121 (2), 1000-1012. DOI: 10.1021/acs.jpcc.6b09113.

(120) Ray, K. G.; Klebanoff, L. E.; Lee, J. R. I.; Stavila, V.; Heo, T. W.; Shea, P.; Baker, A. A.; Kang, S.; Bagge-Hansen, M.; Liu, Y. S.; White, J. L.; Wood, B. C. Elucidating the mechanism of MgB2 initial hydrogenation via a combined experimental-theoretical study. Physical Chemistry Chemical Physics 2017, 19 (34), 22646-22658. DOI: 10.1039/c7cp03709k.

(121) Perez-Pimienta, J. A.; Sathitsuksanoh, N.; Thompson, V. S.; Tran, K.; Ponce-Noyola, T.; Stavila, V.; Singh, S.; Simmons, B. A. Ternary ionic liquid-water pretreatment systems of an agave bagasse and municipal solid waste blend. Biotechnology for Biofuels 2017, 10. DOI: 10.1186/s13068-017-0758-4.

(122) Kweon, K. E.; Varley, J. B.; Shea, P.; Adelstein, N.; Mehta, P.; Heo, T. W.; Udovic, T. J.; Stavila, V.; Wood, B. C. Structural, Chemical, and Dynamical Frustration: Origins of Superionic Conductivity in closo-Borate Solid Electrolytes. Chemistry of Materials 2017, 29 (21), 9142-9153. DOI: 10.1021/acs.chemmater.7b02902.

(123) Dolgopolova, E. A.; Brandt, A. J.; Ejegbavwo, O. A.; Duke, A. S.; Maddumapatabandi, T. D.; Galhenage, R. P.; Larson, B. W.; Reid, O. G.; Ammal, S. C.; Heyden, A.; Chandrashekhar, M.; Stavila, V.; Chen, D. A.; Shustova, N. B. Electronic Properties of Bimetallic Metal-Organic Frameworks (MOFs): Tailoring the Density of Electronic States through MOF Modularity. Journal of the American Chemical Society 2017, 139 (14), 5201-5209. DOI: 10.1021/jacs.7b01125.

(124) Chae, J.; An, S.; Ramer, G.; Stavila, V.; Holland, G.; Yoon, Y.; Talin, A. A.; Allendorf, M.; Aksyuk, V. A.; Centrone, A. Nanophotonic Atomic Force Microscope Transducers Enable Chemical Composition and Thermal Conductivity Measurements at the Nanoscale. Nano Letters 2017, 17 (9), 5587-5594. DOI: 10.1021/acs.nanolett.7b02404.

(125) Bukovsky, E. V.; Peryshkov, D. V.; Wu, H.; Zhou, W.; Tang, W. S.; Jones, W. M.; Stavila, V.; Udovic, T. J.; Strauss, S. H. Comparison of the Coordination of B12F122-, B12Cl122-, and B12H122- to Na+ in the Solid State: Crystal Structures and Thermal Behavior of Na2(B12F12), Na2(H2O)4(B12F12), Na2(B12Cl12), and Na2(H2O)6(B12Cl12). Inorganic Chemistry 2017, 56 (8), 4369-4379. DOI: 10.1021/acs.inorgchem.6b02920.

(126) Zhou, X. W.; El Gabaly, F.; Stavila, V.; Allendorf, M. D. Molecular Dynamics Simulations of Hydrogen Diffusion in Aluminum. Journal of Physical Chemistry C 2016, 120 (14), 7500-7509. DOI: 10.1021/acs.jpcc.6b01802.

(127) Wu, H.; Tang, W. S.; Zhou, W.; Tarver, J. D.; Stavila, V.; Brown, C. M.; Udovic, T. J. The low-temperature structural behavior of sodium 1-carba-closo-decaborate: NaCB9H10. Journal of Solid State Chemistry 2016, 243, 162-167. DOI: 10.1016/j.jssc.2016.08.024.

(128) White, J. L.; Newhouse, R. J.; Zhang, J. Z.; Udovic, T. J.; Stavila, V. Understanding and Mitigating the Effects of Stable Dodecahydro-closo-dodecaborate Intermediates on Hydrogen-Storage Reactions. Journal of Physical Chemistry C 2016, 120 (45), 25725-25731. DOI: 10.1021/acs.jpcc.6b09789.

(129) Ullman, A. M.; Brown, J. W.; Foster, M. E.; Léonard, F.; Leong, K.; Stavila, V.; Allendorf, M. D. Transforming MOFs for Energy Applications Using the Guest@MOF Concept. Inorganic Chemistry 2016, 55 (15), 7233-7249. DOI: 10.1021/acs.inorgchem.6b00909.

(130) Tang, W. S.; Yoshida, K.; Soloninin, A. V.; Skoryunov, R. V.; Babanova, O. A.; Skripov, A. V.; Dimitrievska, M.; Stavila, V.; Orimo, S.; Udovic, T. J. Stabilizing Superionic-Conducting Structures via Mixed-Anion Solid Solutions of Monocarba-closo-borate Salts. Acs Energy Letters 2016, 1 (4), 659-664. DOI: 10.1021/acsenergylett.6b00310.

(131) Tang, W. S.; Matsuo, M.; Wu, H.; Stavila, V.; Zhou, W.; Talin, A. A.; Soloninin, A. V.; Skoryunov, R. V.; Babanova, O. A.; Skripov, A. V.; Unemoto, A.; Orimo, S. I.; Udovic, T. J. Liquid-Like Ionic Conduction in Solid Lithium and Sodium Monocarba-closo-Decaborates Near or at Room Temperature. Advanced Energy Materials 2016, 6 (8). DOI: 10.1002/aenm.201502237.

(132) Tang, W. S.; Matsuo, M.; Wu, H.; Stavila, V.; Zhou, W.; Talin, A. A.; Soloninin, A. V.; Skoryunov, R. V.; Babanova, O. A.; Skripov, A. V.; Unemoto, A.; Orimo, S.; Udovic, T. J. Liquid-like Ionic Conduction in Solid Lithium and Sodium Monocarba-closo-decaborates near or at Room Temperature (vol 6, 1502237, 2016). Advanced Energy Materials 2016, 6 (24). DOI: 10.1002/aenm.201602386.

(133) Stavila, V.; Schneider, C.; Mowry, C.; Zeitler, T. R.; Greathouse, J. A.; Robinson, A. L.; Denning, J. M.; Volponi, J.; Leong, K.; Quan, W.; Tu, M.; Fischer, R. A.; Allendorf, M. D. Thin Film Growth of nbo MOFs and their Integration with Electroacoustic Devices. Advanced Functional Materials 2016, 26 (11), 1699-1707. DOI: 10.1002/adfm.201504211.

(134) Stavila, V.; Parthasarathi, R.; Davi, R. W.; El Gabaly, F.; Sale, K. L.; Simmons, B. A.; Singh, S.; Allendorf, M. D. MOF-Based Catalysts for Selective Hydrogenolysis of Carbon Oxygen Ether Bonds. Acs Catalysis 2016, 6 (1), 55-59. DOI: 10.1021/acscatal.5b02061.

(135) Perez-Pimienta, J. A.; Poggi-Varaldo, H. M.; Ponce-Noyola, T.; Ramos-Valdivia, A. C.; Chavez-Carvayar, J. A.; Stavila, V.; Simmons, B. A. Fractional pretreatment of raw and calcium oxalate-extracted agave bagasse using ionic liquid and alkaline hydrogen peroxide. Biomass & Bioenergy 2016, 91, 48-55. DOI: 10.1016/j.biombioe.2016.05.001.

(136) Jones, C. G.; Stavila, V.; Conroy, M. A.; Feng, P.; Slaughter, B. V.; Ashley, C. E.; Allendorf, M. D. Versatile Synthesis and Fluorescent Labeling of ZIF-90 Nanoparticles for Biomedical Applications. Acs Applied Materials & Interfaces 2016, 8 (12), 7623-7630. DOI: 10.1021/acsami.5b11760.

(137) Dimitrievska, M.; White, J. L.; Zhou, W.; Stavila, V.; Klebanoff, L. E.; Udovic, T. J. Structure-dependent vibrational dynamics of Mg(BH4)2 polymorphs probed with neutron vibrational spectroscopy and first-principles calculations. Physical Chemistry Chemical Physics 2016, 18 (36), 25546-25552. DOI: 10.1039/c6cp04469g.

(138) Allendorf, M. D.; Stavila, V. NANOPOROUS FILMS From conventional to conformal. Nature Materials 2016, 15 (3), 255-257. DOI: 10.1038/nmat4527.

(139) Yang, N.; Yee, J. K.; Zhang, Z. H.; Kurmanaeva, L.; Cappillino, P.; Stavila, V.; Lavernia, E. J.; Marchi, C. S. Hydrogen sorption characteristics of nanostructured Pd-10Rh processed by cryomilling. Acta Materialia 2015, 82, 41-50. DOI: 10.1016/j.actamat.2014.08.056.

(140) Wu, H.; Tang, W. S.; Zhou, W.; Stavila, V.; Rush, J. J.; Udovic, T. J. The structure of monoclinic Na2B10H10: a combined diffraction, spectroscopy, and theoretical approach. Crystengcomm 2015, 17 (18), 3533-3540. DOI: 10.1039/c5ce00369e.

(141) Wu, H.; Tang, W. S.; Stavila, V.; Zhou, W.; Rush, J. J.; Udovic, T. J. Structural Behavior of Li2B10H10. Journal of Physical Chemistry C 2015, 119 (12), 6481-6487. DOI: 10.1021/acs.jpcc.5b00533.

(142) Unemoto, A.; Ikeshoji, T.; Yasaku, S.; Matsuo, M.; Stavila, V.; Udovic, T. J.; Orimo, S. Stable Interface Formation between TiS2 and LiBH4 in Bulk-Type All-Solid-State Lithium Batteries. Chemistry of Materials 2015, 27 (15), 5407-5416. DOI: 10.1021/acs.chemmater.5b02110.

(143) Tang, W. S.; Unemoto, A.; Zhou, W.; Stavila, V.; Matsuo, M.; Wu, H.; Orimo, S.; Udovic, T. J. Unparalleled lithium and sodium superionic conduction in solid electrolytes with large monovalent cage-like anions. Energy & Environmental Science 2015, 8 (12), 3637-3645. DOI: 10.1039/c5ee02941d.

(144) Tang, W. S.; Udovic, T. J.; Stavila, V. Altering the structural properties of A2B12H12 compounds via cation and anion modifications. Journal of Alloys and Compounds 2015, 645, S200-S204. DOI: 10.1016/j.jallcom.2015.01.061.

(145) Skripov, A. V.; Skoryunov, R. V.; Soloninin, A. V.; Babanova, O. A.; Tang, W. S.; Stavila, V.; Udovic, T. J. Anion Reorientations and Cation Diffusion in LiCB11H12 and NaCB11H12: 1H, 7Li, and 23Na NMR Studies. Journal of Physical Chemistry C 2015, 119 (48), 26912-26918. DOI: 10.1021/acs.jpcc.5b10055.

(146) Shi, J.; George, K. W.; Sun, N.; He, W.; Li, C. L.; Stavila, V.; Keasling, J. D.; Simmons, B. A.; Lee, T. S.; Singh, S. Impact of Pretreatment Technologies on Saccharification and Isopentenol Fermentation of Mixed Lignocellulosic Feedstocks. Bioenergy Research 2015, 8 (3), 1004-1013. DOI: 10.1007/s12155-015-9588-z.

(147) Scullin, C.; Stavila, V.; Skarstad, A.; Keasling, J. D.; Simmons, B. A.; Singh, S. Optimization of renewable pinene production from the conversion of macroalgae Saccharina latissima. Bioresource Technology 2015, 184, 415-420. DOI: 10.1016/j.biortech.2014.09.105.

(148) Reyes-Gil, K. R.; Stephens, Z. D.; Stavila, V.; Robinson, D. B. Composite WO3/TiO2 Nanostructures for High Electrochromic Activity. Acs Applied Materials & Interfaces 2015, 7 (4), 2202-2213. DOI: 10.1021/am5050696.

(149) Perez-Pimienta, J. A.; Lopez-Ortega, M. G.; Chavez-Carvayar, J. A.; Varanasi, P.; Stavila, V.; Cheng, G.; Singh, S.; Simmons, B. A. Characterization of agave bagasse as a function of ionic liquid pretreatment. Biomass & Bioenergy 2015, 75, 180-188. DOI: 10.1016/j.biombioe.2015.02.026.

(150) George, A.; Brandt, A.; Tran, K.; Zahari, S.; Klein-Marcuschamer, D.; Sun, N.; Sathitsuksanoh, N.; Shi, J.; Stavila, V.; Parthasarathi, R.; Singh, S.; Holmes, B. M.; Welton, T.; Simmons, B. A.; Hallett, J. P. Design of low-cost ionic liquids for lignocellulosic biomass pretreatment. Green Chemistry 2015, 17 (3), 1728-1734. DOI: 10.1039/c4gc01208a.

(151) Erickson, K. J.; Léonard, F.; Stavila, V.; Foster, M. E.; Spataru, C. D.; Jones, R. E.; Foley, B. M.; Hopkins, P. E.; Allendorf, M. D.; Talin, A. A. Thin Film Thermoelectric Metal-Organic Framework with High Seebeck Coefficient and Low Thermal Conductivity. Advanced Materials 2015, 27 (22), 3453-3459. DOI: 10.1002/adma.201501078.

(152) Davidovich, R. L.; Marinin, D. V.; Stavila, V.; Whitmire, K. H. Structural chemistry of fluoride and oxofluoride complexes of titanium(IV). Coordination Chemistry Reviews 2015, 299, 61-82. DOI: 10.1016/j.ccr.2015.04.002.

(153) Allendorf, M. D.; Stavila, V. Crystal engineering, structure-function relationships, and the future of metal-organic frameworks. Crystengcomm 2015, 17 (2), 229-246. DOI: 10.1039/c4ce01693a.

(154) Allendorf, M. D.; Foster, M. E.; Léonard, F.; Stavila, V.; Feng, P. L.; Doty, F. P.; Leong, K.; Ma, E. Y.; Johnston, S. R.; Talin, A. A. Guest-Induced Emergent Properties in Metal-Organic Frameworks. Journal of Physical Chemistry Letters 2015, 6 (7), 1182-1195. DOI: 10.1021/jz5026883.

(155) Verdal, N.; Udovic, T. J.; Stavila, V.; Tang, W. S.; Rush, J. J.; Skripov, A. V. Anion Reorientations in the Superionic Conducting Phase of Na2B12H12. Journal of Physical Chemistry C 2014, 118 (31), 17483-17489. DOI: 10.1021/jp506252c.

(156) Verdal, N.; Her, J. H.; Stavila, V.; Soloninin, A. V.; Babanova, O. A.; Skripov, A. V.; Udovic, T. J.; Rush, J. J. Complex high-temperature phase transitions in Li2B12H12 and Na2B12H12. Journal of Solid State Chemistry 2014, 212, 81-91. DOI: 10.1016/j.jssc.2014.01.006.

(157) Udovic, T. J.; Matsuo, M.; Unemoto, A.; Verdal, N.; Stavila, V.; Skripov, A. V.; Rush, J. J.; Takamura, H.; Orimo, S. Sodium superionic conduction in Na2B12H12. Chemical Communications 2014, 50 (28), 3750-3752. DOI: 10.1039/c3cc49805k.

(158) Udovic, T. J.; Matsuo, M.; Tang, W. S.; Wu, H.; Stavila, V.; Soloninin, A. V.; Skoryunov, R. V.; Babanova, O. A.; Skripov, A. V.; Rush, J. J.; Unemoto, A.; Takamura, H.; Orimo, S. Exceptional Superionic Conductivity in Disordered Sodium Decahydro-closo-decaborate. Advanced Materials 2014, 26 (45), 7622-7626. DOI: 10.1002/adma.201403157.

(159) Talin, A. A.; Centrone, A.; Ford, A. C.; Foster, M. E.; Stavila, V.; Haney, P.; Kinney, R. A.; Szalai, V.; El Gabaly, F.; Yoon, H. P.; Léonard, F.; Allendorf, M. D. Tunable Electrical Conductivity in Metal-Organic Framework Thin-Film Devices. Science 2014, 343 (6166), 66-69. DOI: 10.1126/science.1246738.

(160) Sun, N.; Parthasarathi, R.; Socha, A. M.; Shi, J.; Zhang, S.; Stavila, V.; Sale, K. L.; Simmons, B. A.; Singh, S. Understanding pretreatment efficacy of four cholinium and imidazolium ionic liquids by chemistry and computation. Green Chemistry 2014, 16 (5), 2546-2557. DOI: 10.1039/c3gc42401d.

(161) Stavila, V.; Talin, A. A.; Allendorf, M. D. MOF-based electronic and optoelectronic devices. Chemical Society Reviews 2014, 43 (16), 5994-6010. DOI: 10.1039/c4cs00096j.

(162) Stavila, V. Structural features of metal dodecahydro-closo-dodecaborates. Acta Crystallographica a-Foundation and Advances 2014, 70, C1026-C1026. DOI: 10.1107/s2053273314089736.

(163) Socha, A. M.; Parthasarathi, R.; Shi, J.; Pattathil, S.; Whyte, D.; Bergeron, M.; George, A.; Tran, K.; Stavila, V.; Venkatachalam, S.; Hahn, M. G.; Simmons, B. A.; Singh, S. Efficient biomass pretreatment using ionic liquids derived from lignin and hemicellulose. Proceedings of the National Academy of Sciences of the United States of America 2014, 111 (35), E3587-E3595. DOI: 10.1073/pnas.1405685111.

(164) Shi, J.; Balamurugan, K.; Parthasarathi, R.; Sathitsuksanoh, N.; Zhang, S.; Stavila, V.; Subramanian, V.; Simmons, B. A.; Singh, S. Understanding the role of water during ionic liquid pretreatment of lignocellulose: co-solvent or anti-solvent? Green Chemistry 2014, 16 (8), 3830-3840. DOI: 10.1039/c4gc00373j.

(165) Sharma, P. A.; Sharma, A. L. L.; Hekmaty, M.; Hattar, K.; Stavila, V.; Goeke, R.; Erickson, K.; Medlin, D. L.; Brahlek, M.; Koirala, N.; Oh, S. Ion beam modification of topological insulator bismuth selenide. Applied Physics Letters 2014, 105 (24). DOI: 10.1063/1.4904936.

(166) Sathitsuksanoh, N.; Holtman, K. M.; Yelle, D. J.; Morgan, T.; Stavila, V.; Pelton, J.; Blanch, H.; Simmons, B. A.; George, A. Lignin fate and characterization during ionic liquid biomass pretreatment for renewable chemicals and fuels production. Green Chemistry 2014, 16 (3), 1236-1247. DOI: 10.1039/c3gc42295j.

(167) Poonyayant, N.; Stavila, V.; Majzoub, E. H.; Klebanoff, L. E.; Behrens, R.; Angboonpong, N.; Ulutagay-Kartin, M.; Pakawatpanurut, P.; Hecht, E. S.; Breit, J. S. An Investigation into the Hydrogen Storage Characteristics of Ca(BH4)2/LiNH2 and Ca(BH4)2/NaNH2: Evidence of Intramolecular Destabilization. Journal of Physical Chemistry C 2014, 118 (27), 14759-14769. DOI: 10.1021/jp502516g.

(168) Jones, C. G.; Cappillino, P. J.; Stavila, V.; Robinson, D. B. Control of both particle and pore size in nanoporous palladium alloy powders. Powder Technology 2014, 267, 95-102. DOI: 10.1016/j.powtec.2014.07.008.

(169) Dougherty, M. J.; Tran, H. M.; Stavila, V.; Knierim, B.; George, A.; Auer, M.; Adams, P. D.; Hadi, M. Z. Cellulosic Biomass Pretreatment and Sugar Yields as a Function of Biomass Particle Size. Plos One 2014, 9 (6). DOI: 10.1371/journal.pone.0100836.

(170) Davidovich, R. L.; Tkachev, V. V.; Logvinova, V. B.; Stavila, V. New structure types of polymeric chain anions in the crystal structures of complex zirconium fluorides. Journal of Structural Chemistry 2014, 55 (6), 1083-1090. DOI: 10.1134/s0022476614060110.

(171) Davidovich, R. L.; Tkachev, V. V.; Logvinova, V. B.; Kostin, V. I.; Stavila, V. Crystal structure of tetramethylammonium fluoridotitanate(IV) with dimeric complex anions of different compositions. Journal of Structural Chemistry 2014, 55 (5), 923-926. DOI: 10.1134/s0022476614050199.

(172) Sun, N.; Liu, H. B.; Sathitsuksanoh, N.; Stavila, V.; Sawant, M.; Bonito, A.; Tran, K.; George, A.; Sale, K. L.; Singh, S.; Simmons, B. A.; Holmes, B. M. Production and extraction of sugars from switchgrass hydrolyzed in ionic liquids. Biotechnology for Biofuels 2013, 6. DOI: 10.1186/1754-6834-6-39.

(173) Stavila, V.; Robinson, D. B.; Hekmaty, M. A.; Nishimoto, R.; Medlin, D. L.; Zhu, S.; Tritt, T. M.; Sharma, P. A. Wet-Chemical Synthesis and Consolidation of Stoichiometric Bismuth Telluride Nanoparticles for Improving the Thermoelectric Figure-of-Merit. Acs Applied Materials & Interfaces 2013, 5 (14), 6678-6686. DOI: 10.1021/am401444w.

(174) Socha, A. M.; Plummer, S. P.; Stavila, V.; Simmons, B. A.; Singh, S. Comparison of sugar content for ionic liquid pretreated Douglas-fir woodchips and forestry residues. Biotechnology for Biofuels 2013, 6. DOI: 10.1186/1754-6834-6-61.

(175) Skripov, A. V.; Babanova, O. A.; Soloninin, A. V.; Stavila, V.; Verdal, N.; Udovic, T. J.; Rush, J. J. Nuclear Magnetic Resonance Study of Atomic Motion in A2B12H12 (A = Na, K, Rb, Cs): Anion Reorientations and Na+ Mobility. Journal of Physical Chemistry C 2013, 117 (49), 25961-25968. DOI: 10.1021/jp4106585.

(176) Perez-Pimienta, J. A.; Lopez-Ortega, M. G.; Varanasi, P.; Stavila, V.; Cheng, G.; Singh, S.; Simmons, B. A. Comparison of the impact of ionic liquid pretreatment on recalcitrance of agave bagasse and switchgrass. Bioresource Technology 2013, 127, 18-24. DOI: 10.1016/j.biortech.2012.09.124.

(177) Liu, X. F.; Majzoub, E. H.; Stavila, V.; Bhakta, R. K.; Allendorf, M. D.; Shane, D. T.; Conradi, M. S.; Verdal, N.; Udovic, T. J.; Hwang, S. J. Probing the unusual anion mobility of LiBH4 confined in highly ordered nanoporous carbon frameworks via solid state NMR and quasielastic neutron scattering. Journal of Materials Chemistry A 2013, 1 (34), 9935-9941. DOI: 10.1039/c3ta12051a.

(178) Ellern, I.; Venkatasubramanian, A.; Lee, J. H.; Hesketh, P.; Stavila, V.; Robinson, A.; Allendorf, M. HKUST-1 coated piezoresistive microcantilever array for volatile organic compound sensing. Micro & Nano Letters 2013, 8 (11), 766-769. DOI: 10.1049/mnl.2013.0390.

(179) Eichorst, S. A.; Varanasi, P.; Stavila, V.; Zemla, M.; Auer, M.; Singh, S.; Simmons, B. A.; Singer, S. W. Community dynamics of cellulose-adapted thermophilic bacterial consortia. Environmental Microbiology 2013, 15 (9), 2573-2587. DOI: 10.1111/1462-2920.12159.

(180) Davidovich, R. L.; Marinin, D. V.; Stavila, V.; Whitmire, K. H. Stereochemistry of fluoride and mixed-ligand fluoride complexes of zirconium and hafnium. Coordination Chemistry Reviews 2013, 257 (21-22), 3074-3088. DOI: 10.1016/j.ccr.2013.06.016.

(181) Cruz, A. G.; Scullin, C.; Mu, C.; Cheng, G.; Stavila, V.; Varanasi, P.; Xu, D. Y.; Mentel, J.; Chuang, Y. D.; Simmons, B. A.; Singh, S. Impact of high biomass loading on ionic liquid pretreatment. Biotechnology for Biofuels 2013, 6. DOI: 10.1186/1754-6834-6-52.

(182) Cappillino, P. J.; Hattar, K. M.; Clark, B. G.; Hartnett, R. J.; Stavila, V.; Hekmaty, M. A.; Jacobs, B. W.; Robinson, D. B. Synthesis of mesoporous palladium with tunable porosity and demonstration of its thermal stability by in situ heating and environmental transmission electron microscopy. Journal of Materials Chemistry A 2013, 1 (3), 602-610. DOI: 10.1039/c2ta00190j.

(183) Venkatasubramanian, A.; Lee, J. H.; Stavila, V.; Robinson, A.; Allendorf, M. D.; Hesketh, P. J. MOF @ MEMS: Design optimization for high sensitivity chemical detection. Sensors and Actuators B-Chemical 2012, 168, 256-262. DOI: 10.1016/j.snb.2012.04.019.

(184) Stavila, V.; Volponi, J.; Katzenmeyer, A. M.; Dixon, M. C.; Allendorf, M. D. Kinetics and mechanism of metal-organic framework thin film growth: systematic investigation of HKUST-1 deposition on QCM electrodes. Chemical Science 2012, 3 (5), 1531-1540. DOI: 10.1039/c2sc20065a.

(185) Stavila, V.; Bhakta, R. K.; Alam, T. M.; Majzoub, E. H.; Allendorf, M. D. Reversible Hydrogen Storage by NaAlH4 Confined within a Titanium-Functionalized MOF-74(Mg) Nanoreactor. Acs Nano 2012, 6 (11), 9807-9817. DOI: 10.1021/nn304514c.

(186) Robinson, A. L.; Stavila, V. L.; Zeitler, T. R.; White, M. I.; Thornberg, S. M.; Greathouse, J. A.; Allendorf, M. D. Ultrasensitive Humidity Detection Using Metal-Organic Framework-Coated Microsensors. Analytical Chemistry 2012, 84 (16), 7043-7051. DOI: 10.1021/ac301183w.

(187) Papa, G.; Varanasi, P.; Sun, L.; Cheng, G.; Stavila, V.; Holmes, B.; Simmons, B. A.; Adani, F.; Singh, S. Exploring the effect of different plant lignin content and composition on ionic liquid pretreatment efficiency and enzymatic saccharification of Eucalyptus globulus L. mutants. Bioresource Technology 2012, 117, 352-359. DOI: 10.1016/j.biortech.2012.04.065.

(188) Luo, W. F.; Stavila, V.; Klebanoff, L. E. New insights into the mechanism of activation and hydrogen absorption of (2LiNH2-MgH2). International Journal of Hydrogen Energy 2012, 37 (8), 6646-6652. DOI: 10.1016/j.ijhydene.2012.01.019.

(189) Liu, H. B.; Cheng, G.; Kent, M.; Stavila, V.; Simmons, B. A.; Sale, K. L.; Singh, S. Simulations Reveal Conformational Changes of Methylhydroxyl Groups during Dissolution of Cellulose Iβ in Ionic Liquid 1-Ethyl-3-methylimidazolium Acetate. Journal of Physical Chemistry B 2012, 116 (28), 8131-8138. DOI: 10.1021/jp301673h.

(190) Lensch-Falk, J. L.; Banga, D.; Hopkins, P. E.; Robinson, D. B.; Stavila, V.; Sharma, P. A.; Medlin, D. L. Electrodeposition and characterization of nano-crystalline antimony telluride thin films. Thin Solid Films 2012, 520 (19), 6109-6117. DOI: 10.1016/j.tsf.2012.05.078.

(191) Her, J. H.; Wu, H.; Verdal, N.; Zhou, W.; Stavila, V.; Udovic, T. J. Structures of the strontium and barium dodecahydro-closo-dodecaborates. Journal of Alloys and Compounds 2012, 514, 71-75. DOI: 10.1016/j.jallcom.2011.10.085.

(192) Cheng, G.; Varanasi, P.; Arora, R.; Stavila, V.; Simmons, B. A.; Kent, M. S.; Singh, S. Impact of Ionic Liquid Pretreatment Conditions on Cellulose Crystalline Structure Using 1-Ethyl-3-methylimidazolium Acetate. Journal of Physical Chemistry B 2012, 116 (33), 10049-10054. DOI: 10.1021/jp304538v.

(193) Cappillino, P. J.; Sugar, J. D.; Hekmaty, M. A.; Jacobs, B. W.; Stavila, V.; Kotula, P. G.; Chames, J. M.; Yang, N. Y.; Robinson, D. B. Nanoporous Pd alloys with compositionally tunable hydrogen storage properties prepared by nanoparticle consolidation. Journal of Materials Chemistry 2012, 22 (28), 14013-14022. DOI: 10.1039/c2jm30988b.

(194) Bhakta, R. K.; Maharrey, S.; Stavila, V.; Highley, A.; Alam, T.; Majzoub, E.; Allendorf, M. Thermodynamics and kinetics of NaAlH4 nanocluster decomposition. Physical Chemistry Chemical Physics 2012, 14 (22), 8160-8169. DOI: 10.1039/c2cp40196g.

(195) Banga, D.; Lensch-Falk, J. L.; Medlin, D. L.; Stavila, V.; Yang, N. Y. C.; Robinson, D. B.; Sharma, P. A. Periodic Modulation of Sb Stoichiometry in Bi2Te3/Bi2-xSbxTe3 Multi layers Using Pulsed Electrodeposition. Crystal Growth & Design 2012, 12 (3), 1347-1353. DOI: 10.1021/cg2014418.

(196) Verdal, N.; Zhou, W.; Stavila, V.; Her, J. H.; Yousufuddin, M.; Yildirim, T.; Udovic, T. J. Alkali and alkaline-earth metal dodecahydro-closo-dodecaborates: Probing structural variations via neutron vibrational spectroscopy. Journal of Alloys and Compounds 2011, 509, S694-S697. DOI: 10.1016/j.jallcom.2010.08.024.

(197) Verdal, N.; Wu, H.; Udovic, T. J.; Stavila, V.; Zhou, W.; Rush, J. J. Evidence of a transition to reorientational disorder in the cubic alkali-metal dodecahydro-closo-dodecaborates. Journal of Solid State Chemistry 2011, 184 (11), 3110-3116. DOI: 10.1016/j.jssc.2011.09.010.

(198) Verdal, N.; Udovic, T. J.; Rush, J. J.; Stavila, V.; Wu, H.; Zhou, W.; Jenkins, T. Low-temperature tunneling and rotational dynamics of the ammonium cations in (NH4)2B12H12. Journal of Chemical Physics 2011, 135 (9). DOI: 10.1063/1.3624495.

(199) Stavila, V.; Bulimestru, I.; Gulea, A.; Colson, A. C.; Whitmire, K. H. Hexaaquacobalt(II) and hexaaquanickel(II) bis(μ-pyridine-2,6-dicarboxylato)bis (pyridine-2,6-dicarboxylato)bismuthate(III) dihydrate. Acta Crystallographica Section C-Crystal Structure Communications 2011, 67, M65-M68. DOI: 10.1107/s0108270110053497.

(200) Shane, D. T.; Rayhel, L. H.; Huang, Z. G.; Zhao, J. C.; Tang, X.; Stavila, V.; Conradi, M. S. Comprehensive NMR Study of Magnesium Borohydride. Journal of Physical Chemistry C 2011, 115 (7), 3172-3177. DOI: 10.1021/jp110762s.

(201) Mandal, T.; Piburn, G.; Stavila, V.; Rusakova, I.; Ould-Ely, T.; Colson, A. C.; Whitmire, K. H. New Mixed Ligand Single-Source Precursors for PbS Nanoparticles and Their Solvothermal Decomposition to Anisotropic Nano- And Microstructures. Chemistry of Materials 2011, 23 (18), 4158-4169. DOI: 10.1021/cm201064c.

(202) Klein, M. P.; Jacobs, B. W.; Ong, M. D.; Fares, S. J.; Robinson, D. B.; Stavila, V.; Wagner, G. J.; Arslan, I. Three-Dimensional Pore Evolution of Nanoporous Metal Particles for Energy Storage. Journal of the American Chemical Society 2011, 133 (24), 9144-9147. DOI: 10.1021/ja200561w.

(203) Allendorf, M. D.; Schwartzberg, A.; Stavila, V.; Talin, A. A. A Roadmap to Implementing Metal-Organic Frameworks in Electronic Devices: Challenges and Critical Directions. Chemistry-a European Journal 2011, 17 (41), 11372-11388. DOI: 10.1002/chem.201101595.

(204) Stavila, V.; Whitmire, K. H. (N,N-Dimethylformamide-κO)bis(3-hydroxypicolinato-κ2N,O2) phenylbismuth(III). Acta Crystallographica Section E-Structure Reports Online 2010, 66, M1547-U1636. DOI: 10.1107/s1600536810044235.

(205) Stavila, V.; Her, J. H.; Zhou, W.; Hwang, S. J.; Kim, C.; Ottley, L. A. M.; Udovic, T. J. Probing the structure, stability and hydrogen storage properties of calcium dodecahydro-closo-dodecaborate. Journal of Solid State Chemistry 2010, 183 (5), 1133-1140. DOI: 10.1016/j.jssc.2010.03.026.

(206) Newhouse, R. J.; Stavila, V.; Hwang, S. J.; Klebanoff, L. E.; Zhang, J. Z. Reversibility and Improved Hydrogen Release of Magnesium Borohydride. Journal of Physical Chemistry C 2010, 114 (11), 5224-5232. DOI: 10.1021/jp9116744.

(207) Luo, W. F.; Cowgill, D.; Stewart, K.; Stavila, V. High capacity hydrogen generation on-demand from (NH3 + LiAlH4). Journal of Alloys and Compounds 2010, 497 (1-2), L17-L20. DOI: 10.1016/j.jallcom.2010.03.040.

(208) Kim, K. C.; Allendorf, M. D.; Stavila, V.; Sholl, D. S. Predicting impurity gases and phases during hydrogen evolution from complex metal hydrides using free energy minimization enabled by first-principles calculations. Physical Chemistry Chemical Physics 2010, 12 (33), 9918-9926. DOI: 10.1039/c001657h.

(209) Davidovich, R. L.; Stavila, V.; Whitmire, K. H. Stereochemistry of lead(II) complexes containing sulfur and selenium donor atom ligands. Coordination Chemistry Reviews 2010, 254 (17-18), 2193-2226. DOI: 10.1016/j.ccr.2010.05.013.

(210) Stavila, V.; Whitmire, K. H.; Rusakova, I. Synthesis of Bi2S3 Nanostructures from Bismuth(III) Thiourea and Thiosemicarbazide Complexes. Chemistry of Materials 2009, 21 (22), 5456-5465. DOI: 10.1021/cm902229x.

(211) Stavila, V.; Thurston, J. H.; Whitmire, K. H. Selective Arylation Reactions of Bismuth-Transition Metal Salicylate Complexes. Inorganic Chemistry 2009, 48 (14), 6945-6951. DOI: 10.1021/ic9010357.

(212) Stavila, V.; Dikarev, E. V. Phenyl bismuth β-diketonate complexes: Synthesis and structural characterization. Journal of Organometallic Chemistry 2009, 694 (18), 2956-2964. DOI: 10.1016/j.jorganchem.2009.04.036.

(213) Mandal, T.; Stavila, V.; Rusakova, I.; Ghosh, S.; Whitmire, K. H. Molecular Precursors for CdS Nanoparticles: Synthesis and Characterization of Carboxylate-Thiourea or -Thiosemicarbazide Cadmium Complexes and Their Decomposition. Chemistry of Materials 2009, 21 (23), 5617-5626. DOI: 10.1021/cm902230u.

(214) Her, J. H.; Zhou, W.; Stavila, V.; Brown, C. M.; Udovic, T. J. Role of Cation Size on the Structural Behavior of the Alkali-Metal Dodecahydro-closo-Dodecaborates. Journal of Physical Chemistry C 2009, 113 (26), 11187-11189. DOI: 10.1021/jp904980m.

(215) Davidovich, R. L.; Stavila, V.; Marinin, D. V.; Voit, E. I.; Whitmire, K. H. Stereochemistry of lead(II) complexes with oxygen donor ligands. Coordination Chemistry Reviews 2009, 253 (9-10), 1316-1352. DOI: 10.1016/j.ccr.2008.09.003.

(216) Stavila, V.; Stortz, Y.; Franc, C.; Pitrat, D.; Maurin, P.; Hasserodt, J. Effective repression of the fragmentation of a hexadentate ligand bearing an auto-immolable pendant arm by iron coordination. European Journal of Inorganic Chemistry 2008,  (25), 3943-3947. DOI: 10.1002/ejic.200800419.

(217) Stavila, V.; Allali, M.; Canaple, L.; Stortz, Y.; Franc, C.; Maurin, P.; Beuf, O.; Dufay, O.; Samarut, J.; Janier, M.; Hasserodt, J. Significant relaxivity gap between a low-spin and a high-spin iron(II) complex of structural similarity: an attractive off-on system for the potential design of responsive MRI probes. New Journal of Chemistry 2008, 32 (3), 428-435. DOI: 10.1039/b715254j.

(218) Maurin, P.; Stavila, V.; Allali, M.; Canaple, L.; Beuf, O.; Stortz, Y.; Samarut, J.; Janier, M.; Hasserodt, J. Studies regarding the adjustment of bioactivable contrast agents with an iron base for in vivo IRM. Bulletin Du Cancer 2008, 95, S24-S25.

(219) Gulea, A.; Poirier, D.; Roy, J.; Stavila, V.; Bulimestru, I.; Tapcov, V.; Birca, M.; Popovschi, L. In vitro antileukemia, antibacterial and antifungal activities of some 3d metal complexes: Chemical synthesis and structure – activity relationships. Journal of Enzyme Inhibition and Medicinal Chemistry 2008, 23 (6), 806-818. DOI: 10.1080/14756360701743002.

(220) Stavila, V.; Thurston, J. H.; Prieto-Centurión, D.; Whitmire, K. H. A new methodology for synthesis of aryl bismuth compounds:: Arylation of bismuth(III) carboxylates by sodium tetraarylborate salts. Organometallics 2007, 26 (27), 6864-6866. DOI: 10.1021/om7009667.

(221) Stavila, V.; Fettinger, J. C.; Whitmire, K. H. Synthesis and characterization of new phenylbis(salicylato)bismuth(III) complexes. Organometallics 2007, 26 (14), 3321-3328. DOI: 10.1021/om070115c.

(222) Stavila, V.; Davidovich, R. L.; Gulea, A.; Whitmire, K. H. Bismuth(III) complexes with aminopolycarboxylate and polyaminopolycarboxylate ligands: Chemistry and structure. Coordination Chemistry Reviews 2006, 250 (21-22), 2782-2810. DOI: 10.1016/j.ccr.2006.02.032.

(223) Filippova, I. G.; Simonov, Y. A.; Gdanets, M.; Stavila, V. Crystal structure of Tris(1,10-phenanthroline)iron(II) dinitrate dihydrate. Journal of Structural Chemistry 2005, 46 (6), 1095-1098. DOI: 10.1007/s10947-006-0249-0.

(224) Stavila, V.; Gulea, A.; Shova, S.; Simonov, Y. A.; Petrenko, P.; Lipkowski, J.; Riblet, F.; Helm, L. An unexpected influence of the nature of the amine on the crystal structure of some Co(III)-Bi(III) heterobimetallic complexes. Inorganica Chimica Acta 2004, 357 (7), 2060-2068. DOI: 10.1016/j.ica.2004.01.025.

(225) Stavila, V.; Gulea, A.; Popa, N.; Shova, S.; Merbach, A.; Simonov, Y. A.; Lipkowski, J. A novel 3D Nd(III)-Bi(III) coordination polymer generated from EDTA ligand. Inorganic Chemistry Communications 2004, 7 (5), 634-637. DOI: 10.1016/j.inoche.2004.03.003.

(226) Petrenko, P. A.; Gdaniec, M.; Simonov, Y. A.; Stavila, V. G.; Gulea, A. P. Crystal structure of monoprotonated Ni(II) nitrilotriacetate tetrahydrate. Russian Journal of Coordination Chemistry 2004, 30 (11), 813-817. DOI: 10.1023/B:RUCO.0000047470.68177.4a.

(227) Stavila, V.; Wignacourt, J. P.; Holt, E. M.; Conflant, P.; Drache, M.; Gulea, A. Synthesis and structure of some Co(III)-Bi(III) heterometallic complexes: Co(NH3)5NCS Bi(EDTA) 2•4H2O, trans-Co(NH3)4(NO2)2 Bi(EDTA)(H2O) •2H2O, and Co(NH3)4(CO3) Bi(EDTA) •3H2O. Inorganica Chimica Acta 2003, 353, 43-50. DOI: 10.1016/s0020-1693(03)00225-1.

(228) Bachman, R. E.; Whitmire, K. H.; Thurston, J. H.; Gulea, A.; Stavila, O.; Stavila, V. Bismuth ladder polymers: structural and thermal studies of Bi(OCH2CH2)3N n and (BixTb1-x(O2C2H2)3N•2H2O n. Inorganica Chimica Acta 2003, 346, 249-255. DOI: 10.1016/s0020-1693(02)01381-6.

(229) Stavila, V.; Gulya, A.; Shova, S.; Gdanec, M.; Simonov, Y. A. Synthesis and study of heterometallic Co-Bi compounds based on ethylenediaminetetraacetic acid.: Crystal and molecular structures of Co(DH)₂(o-NH2C6H4CH3)2 2 Bi2(μ-Edta)2(H2O)2 •10H2O. Russian Journal of Coordination Chemistry 2002, 28 (8), 565-572. DOI: 10.1023/a:1019709713657.

(230) Stavila, V.; Gdanec, M.; Shova, S.; Simonov, Y. A.; Gulya, A.; Vignacourt, J. P. Synthesis and structure of {μ-oxalato-bis ethylenediaminetetraacetato-bismuthato(III) }pentaamminethiocyanatocobalt(III) dodecahydrate, Co(NH3)5NCS 2 (Edta)Bi(μ-C2O4)Bi(Edta) •12H2O. Russian Journal of Coordination Chemistry 2000, 26 (10), 741-747.

• V. Stavila, J.L. White, US Patent US Patent # 11267702 granted on 03/08/2022 (2022). “Solid state synthesis of metal borohydrides”
• M. Witman, V. Stavila, Sandia Disclosure #16135  (2022). “Hydrogen Compression and Storage Systems”
• V. Stavila, L.E. Klebanoff, US Patent 11,192,783 granted on 12/07/2021 (2021). “Ternary Borides and Borohydrides for Hydrogen Storage and Method of Synthesis”
• V. Stavila, L.E. Klebanoff, US Patent # 10000377 granted on 06/19/2018 (2018). “Nanostructured Metal Amides and Nitrides for Hydrogen Storage”
• M.S. Kent, M.D. Allendorf, V. Stavila, US Patent  # 9,718,748 granted on 08/01/2017  (2017). “Metal-Organic Framework Catalysts for Selective Cleavage of Aryl-Ether Bonds”
• M.D. Allendorf, A.A. Talin, F. Leonard, V. Stavila, US Patent # 9711743 granted on 07/18/2017 (2017). “Reconfigurable Electronics Using Conducting Metal-Organic Frameworks”
• M.D. Allendorf, F. Leonard, A.A. Talin, V. Stavila, US Patent # 9428525 granted on 8/30/2016  (2016). “Tunable Electrical Conductivity in Metal-Organic Framework Thin Film Devices”
• M.D. Allendorf, V. Stavila, US Patent Application # 14/991734 (2014). “Metal-Organic Framework Catalysts for Selective Cleavage of Aryl-Ether Bonds”
• M.D. Allendorf, A.A. Talin, F. Leonard, V. Stavila, US Patent Application # 14/573990 (2014)….“Multiaxis Sensing Using Electrically Conductive Metal-Organic Frameworks”
• S. Baranov, B. Cinic, I. Redwing, Vitalie Stavila, Moldovan Patent MD-2937  (2006). “Process for Cleaning Machining Attachments from Waste after Epitaxial Growth of Semiconductor Layers”
• A. Gulea, A. Cecal, A. Paraschivescu, V. Stavila, V. Tapcov, N. Popa, Moldovan Patent MD-2673 (2005). “Lanthanum Bismuthate as Catalyst for Water Radiolysis”
• A. Gulea, D. Poirier, J. Roy, V. Stavila, V. Tapcov, Moldovan Patent MD-2786 (2005). “Inhibitors of Human Myeloid Leukemia Based on Heteronuclear Coordination Compounds of Cobalt(III) and Bismuth(III)”
• A. Gulea, V. Stavila, V. Tapcov, I. Bulimestru, Moldovan Patent MD-2479 (2004). “Dodecahydrate of (diethylene-triamine-penta-acetato)bismuthate(III) of Hexaaminocobalt(III) as a Dielectric Material”
• A. Gulea, V. Stavila, V. Tapcov, A. Paraschivescu, A. Cecal, Moldovan Patent MD-2450 (2004). “Catalyst for Radiolytic Decomposition of Water for Hydrogen Production”
• A. Gulea, V. Stavila, V. Tapcov,  Moldovan Patent MD-2240 (2003). “Tris(thiosemicarbazide)cobalt(III) bis(nitrilotriacetato)bismuthate(III) Nonahydrate as a Dielectric Material”
• A. Gulea, V. Stavila, V. Tapcov, Moldovan Patent MD-2146 (2003). “Dielectric Materials Based on Heteronuclear Coordination Complexes of Cobalt(III) and Bismuth(III)”
• A. Gulea, V. Stavila, I. Bulimestru, J.-P. Wignacourt, V. Tapcov. Moldovan Patent MD-1559 (2000). “Process for Obtaining Bismuth Cuprate”

1. Vitalie Stavila, Claudia, Zlotea, Vladimir Yartys, “Prospects and Future Directions for Metal Hydrides in Hydrogen Storage” in Metal Hydrides for Hydrogen-Based Energy Storage: Applications, Ed. Volodimir Yartys, Elsevier, 2025, 548 pages.
2. V. Stavila, L.E. Klebanoff, J.J. Vajo, P. Chen, “Development of On-Board Reversible Complex Metal Hydrides for Hydrogen Storage” in Hydrogen Storage Technology:  Materials and Applications, Ed. L.E. Klebanoff, Taylor and Francis, Boca Raton,2012, pages 133-213.
3. V. Stavila, L.E. Klebanoff, “Hydrogen – Metal hydride storage” in “Hydrogen: Data, Facts and Figures”, Eds. D. Stolten and R.C. Samsun, Wiley-VCH, Dortmund, 2015, pages 79–93.