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Oak Ridge National Laboratory (ORNL) Journal Articles and Books


2022-01Agent-Based Distributed Energy Resources for Supporting Intelligence at the Grid EdgeM. Starke et al.IEEE Journal of Emerging and Selected Topics in Industrial Electronics
Vol. 3, No. 1, pp. 69-78
DOI: 10.1109/JESTIE.2021.3110737
2021-12-06Heavily Tungsten-Doped Sodium Thioantimonate Solid-State Electrolytes with Exceptionally Low Activation Energy for Ionic DiffusionX. Feng, H. Fang, P. Liu, N. Wu, E. Self, L. Yin, P. Wang, X. Li, P. Jena, J. Nanda, D. MitlinAngewandte Chemie International Edition
Vol. 60, Issue 50, pp, 26158-26166
DOI: 10.1002/anie.202110699
2021-08-30Ambient Temperature Sodium Polysulfide Catholyte for Nonaqueous Redox Flow BatteriesE.C. Self, J.L. Tyler, J. NandaJ. Electrochem. Soc.
168 080540
DOI: 10.1149/1945-7111/ac1e57
2021-04Overcharge-to-Thermal-Runaway Behavior and Safety Assessment of Commercial Lithium-ion Cells with Different Cathode Materials: A Comparison StudyZ. Wang, J. Yuan, X. Zhu, H. Wang, L. Huang, Y. Wang, S. XuJournal of Energy Chemistry
55 (2021) 484-498
DOI: 10.1016/j.jechem.2020.07.028
2021-03Anomalously High Elastic Modulus of a poly(ethylene oxide)-based Composite ElectrolyteG. Yang, M.L. Lehmann, S. Zhao, B. Li, S. Ge, P. Cao, F.M. Delnick, A.P. Sokolov, T. Saito, J. NandaEnergy Storage Materials
35 (2021): 431-442
DOI: 10.1016/j.ensm.2020.11.031
2021-01-22Effects of short-term over-discharge cycling on the performance of commercial 21,700 lithium-ion cells and the identification of degradation modesZ. Wang, S. Xu, X. Zhu, H. Wang, L. Huang, J. Yuan, W. YangJournal of Energy Storage
Vol. 35 (2021) 102257
DOI: 10.1016/j.est.2021.102257
2020-09-18Temperature‐dependent Battery Performance of a Na3V2(PO4)2F3@MWCNT Cathode and In‐situ Heat Generation on CyclingR. Amin, I. Belharouak, H.B. Yahia, K. Maher, A. Abouimrane, Y. Zakaria, M. Li, R. EssehliChemSusChem
2020, 13, 5031–5040
DOI: 10.1002/cssc.202001268
2020-08-18Iron-Doped Sodium Vanadium Oxyflurophosphate Cathodes for Sodium-Ion Batteries—Electrochemical Characterization and In Situ Measurements of Heat GenerationI. Belharouak, R. Amin, N. Muralidharan, K. Maher, A. Abouimrane, H.B. Yahia, A. Mahmoud, R. Kumar, R. EssehliACS Appl. Mater. Interfaces
2020, 12, 37, 41765–41775
DOI: 10.1021/acsami.0c11616
2020-07-31Investigation on Capacity Loss Mechanisms of Lithium-ion Pouch Cells under Mechanical Indentation ConditionsX. Zhu, Hsin Wang, S. Allu, Y. Gao, E. Cakmak, E.J. Hopkins, G.M. Veith, Z. WangJournal of Power Sources
465 (2020) 228314
DOI: 10.1016/j.jpowsour.2020.228314
2020-05-12Increasing Compressed Gas Energy Storage Density Using CO2 –N2 Gas MixtureA. Abuheiba, M.R. Ally, B. Smith, A. MomenEnergies
2020, 13(10), 2431
DOI: 10.3390/en13102431
2020-05-05High Capacity Adsorption—Dominated Potassium and Sodium Ion Storage in Activated Crumpled GrapheneB. Lee, M. Kim, S. Kim, J. Nanda, S.J. Kwon, H.D. Jang, D. Mitlin, S.W. LeeAdv. Energy Mater.
2020, 10, 1903280
DOI: 10.1002/aenm.201903280
2020-05-05Eutectic Synthesis of P2-Type NaxFe1/2Mn1/2O2 Cathode with Improved Cell Design for Sodium-ion BatteriesM. Li, D.L. Wood, Y. Bai, R. Essehli, R. Amin, C. Jafta, N. Muralidharan, J. Li, I. BelharouakACS Appl. Mater. Interfaces
2020, 12, 21, 23951–23958
DOI: 10.1021/acsami.0c04513
2020-04-22Electrochemical studies of a high voltage Na4Co3(PO4)2P2O7–MWCNT composite through a selected stable electrolyteP.R. Kumar, R. Essehli, H.B. Yahia, R. Amin, I. BelharouakRSC Adv.
2020, 10, 15983-15989
DOI: 10.1039/D0RA02349C
2020-04-15Internal Short Circuit and Failure Mechanisms of Lithium-ion Pouch Cells under Mechanical Indentation Abuse Conditions: An Experimental StudyX. Zhu, H. Wang, X. Wang, Y. Gao, S. Allu, E. Cakmak, Z. WangJ. of Power Sources
455 (2020) 227939
DOI: 10.1016/j.jpowsour.2020.227939
2020-03-19Well-designed Crosslinked Polymer Electrolyte Enables High Ionic Conductivity and Enhanced Salt SolvationM. Lehmann, G. Yang, J. Nanda, T. SaitoJ. Electrochem. Soc.
167 070539
DOI: 10.1149/1945-7111/ab7c6e
2020-02-20Dendrite‐Free Potassium Metal Anodes in a Carbonate ElectrolyteP. Liu, J. NandaAdv. Mater.
2020, 32, 1906735
DOI: 10.1002/adma.201906735
2019-12-09Site-Specific Sodiation Mechanisms of Selenium in Microporous Carbon HostF. Perras, E. Self, J. NandaNano Lett.
2020, 20, 2, 918–928
DOI: 10.1021/acs.nanolett.9b03797
2019-11-26Electrochemical investigations of high-voltage Na4Ni3(PO4)2P2O7 cathode for sodium-ion batteriesP.R. Kumar, H.B. Yahia, I. Belharouak, R. Amin, R. EssehliJ Solid State Electrochem
24, 17–24 (2020)
DOI: 10.1007/s10008-019-04448-6
2019-10-03High-Capacity Organic Radical Mediated Phosphorus Anode for Sodium-Based Redox Flow BatteriesE. Self, F. Delnick, R. Ruther, S. Allu, J. NandaACS Energy Lett.
2019, 4, 11, 2593–2600
DOI: 10.1021/acsenergylett.9b01744
2019-09-25Materials and Engineering Endeavors Towards Practical Sodium-Ion BatteriesM. Li, Z. Du, M.A. Khaleel, I. BelharouakEnergy Storage Materials
25, 520-536 (2020)
DOI: 10.1016/j.ensm.2019.09.030
2019-06-21Tailored crosslinking of Poly(ethylene oxide) enables mechanical robustness and improved sodium-ion conductivityM. Lehmann, G. Yang, D. Gilmer, K. Sung Han, E. Self, R. Ruther, S. Ge, B. Li, V. Murugesan, A. Sokolov, F. Delnick, J. Nanda, T. SaitoEnergy Storage Materials
21 (2019) 85-96
DOI: 10.1016/j.ensm.2019.06.028
2019-05-01Ion transport and association study of glyme-based electrolytes with lithium and sodium saltsDaniel Morales, Rose E. Ruther, Jagjit Nanda, Steven GreenbaumElectrochimica Acta
304 (2019) 239-245
DOI: 10.1016/j.electacta.2019.02.110
2019-02-15Overcharge investigation of large format lithium-ion pouch cells with Li(Ni0.6Co0.2Mn0.2)O2 cathode for electric vehicles: Thermal runaway features and safety management methodXiaoqing Zhu, Zhenpo Wang, Yituo Wang, Hsin Wang, Cong Wang, Lei Tong, Mi YiEnergy Volume
169 (2019) 868-880
DOI: 10.1016/
2018-10-09Rechargeable redox flow batteries: flow fields, stacks and design considerationsXinyou Ke, Joseph M. Prahl, J. Iwan D. Alexander, Jesse S. Wainright, Thomas A. Zawodzinski, Robert F. SavinellChemistry Society Reviews
2018,47, 8721-8743
DOI: 10.1039/C8CS00072G
2018-09-12Mechanically Robust, Sodium-Ion Conducting Membranes for Nonaqueous Redox Flow BatteriesRuther, R., Yang, G., Delnick, F. M., Tang, Z., Lehmann, M., Saito, T., Meng, Y., Zawodzinski, T. A., Nanda, J.ACS Energy Lett.
2018, 3, 7, 1640–1647
DOI: 10.1021/acsenergylett.8b00680
2018-09-10Grid Energy-Storage Projects: Engineers Building and Using Knowledge in Emerging ProjectsJ. Araiza, J. Hambrick, J. Moon, M. Starke, C. VartanianIEEE Electrific. Mag.
Vol. 6, No. 3, pp. 14-19
DOI: 10.1109/MELE.2018.2849842
2018-08-20The ion and water transport properties of K+ and Na+ form perfluorosulfonic acid polymerJing Penga, Mengkun Tian, Nelly M. Cantillo, Thomas ZawodzinskiElectrochimica Acta
282 (2018) 544-554
DOI: 10.1016/j.electacta.2018.06.035
2017-06-15Effects of sulfonated side chains used in polysulfone based PEMs for VRFB separatorB. Gindt, Z. Tang, D. Watkins D. Abebe S. Seo S. Tuli H. Ghassemi T. Zawodzinski T. FujiwaraJournal of Membrane Science
532 (2017) 58-67
DOI: 10.1016/j.memsci.2017.03.013
2017-05-20Species Uptake and Mass Transport in Membranes for Vanadium Redox Flow BatteriesR. Elgammal Z. Tang Che-Nan Sun J. Lawton T. ZawodzinskiElectrochimica Acta
237 (2017) 1-11
DOI: 10.1016/j.electacta.2017.03.131
2017-05-20High Performance Redox Flow Batteries: An Analysis of the Upper Performance Limits of Flow Batteries Using Non-aqueous SolventsC.-N.Sun M.M.Mench T.A.ZawodzinskiElectrochimica Acta
237 (2017) 199-206
DOI: 10.1016/j.electacta.2017.03.132
2016-02-16Nanoporous polysulfone membranes via a degradable block copolymer precursor for redox flow batteriesB. P. Gindt, D. G. Abebe, Z. J. Tang, M. B. Lindsey, J. Chen, R. A. Elgammal, T. A. Zawodzinski T. FujiwaraJ. Mater. Chem. A
2016,4, 4288-4295
DOI: 10.1039/C6TA00698A
2015-12-28Characterization of Vanadium Ion Uptake in Sulfonated Diels Alder Poly(phenylene) MembranesJ. Lawton, A. Jones, Z. Tang, M. Lindsey, C. Fujimoto, T. ZawodzinskiJ. Electrochem. Soc.
Vol. 163, A5229-A5235
DOI: 10.1149/2.0291601jes
2015-11-21The Cell-in-Series Method: A Technique for Accelerated Electrode Degradation in Redox Flow BatteriesA. Pezeshki, R. Sacci, G. Veith, T. Zawodzinski, M. MenchJ. Electrochem. Soc.
Vol. 163, A5202-A5210
DOI: 10.1149/2.0251601jes
2015-11-19In Situ Potential Distribution Measurement and Validated Model for All-Vanadium Redox Flow BatteryY. A. Gandomi, D. S. Aaron, T. A. Zawodzinski, and M. M. MenchJ. Electrochem. Soc.
Vol. 163, A5188-A5201
DOI: 10.1149/2.0211601jes
2015-11-14Full Cell Study of Diels Alder Poly(phenylene) Anion and Cation Exchange Membranes in Vanadium Redox Flow BatteriesA. M. Pezeshki , Z. J. Tang, C. Fujimoto, C.-N. Sun, M. M. Mench, and T. A. ZawodzinskiJ. Electrochem. Soc.
Vol. 163, A5154-A5162
DOI: 10.1149/2.0201601jes
2014-09-03Characterization of Sulfonated Diels-Alder Poly(phenylene) Membranes for Electrolyte Separators in Vanadium Redox Flow BatteriesZ. Tang, J. Lawton, C. Sun, et alJ. Electrochem. Soc.
Vol. 161, Issue 12, A1860-A1868
DOI: 10.1149/2.0631412jes
2014-06Evaluation of Diels-Alder poly (phenylene) anion exchange membranes in all-vanadium redox flow batteriesC. Sun, Z. Tang, C. Belcher, et al.Electrochemistry Communications
43 (2014) 63-66
DOI: 10.1016/j.elecom.2014.03.010
2014-04-30Resolving Losses at the Negative Electrode in All-Vanadium Redox Flow Batteries Using Electrochemical Impedance SpectroscopyC. Sun, F. Delnick, D. Aaron, et al.J. Electrochem. Soc.
161 A981
DOI: 10.1149/2.045406jes
2014-02-15Hydrogen Evolution at the Negative Electrode of the All-Vanadium Redox Flow BatteriesC. Sun, F. Delnick, L. Baggetto, G. Veith, T. ZawodzinskiJ. Power Sources
248 (2014), 560-564
DOI: 10.1016/j.jpowsour.2013.09.125
2014-02-14Factors Enabling High Mobility of Protons and Water in Perfluorosulfonate Membranes Under Low Hydration ConditionsMaalouf, M., Sun, C., Pyle, B., Emery, M., Haugen, G., Hamrock, S., Zawodzinski Jr., T.International Journal of Hydrogen Energy
39 (2014) 2795-2800
DOI: 10.1016/j.ijhydene.2013.11.006
2014-02-15Electrochemistry and Morphology Studies of Aluminum Plating/Stripping in a Chloroaluminate Ionic Liquid on Porous Carbon MaterialsM. Zhang, J. Watson, R. Counce, P. Trulove, T. ZawodzinskiJ. Electrochem. Soc.
161, D163
DOI: 10.1149/2.048404jes
2013-11-07In Situ Formation of Micron-Scale Li-Metal Anodes with High CyclabilityArruda, T., Lawton, J.,Kumar, A.,Unocic, R.,Kravchenco, I.,Zawodzinski, T.,Jesse, S.,Kalinin,S.,Balke, N.ECS Electrochem. Lett.
Vol. 3, No. 1, pp. A4-A7
DOI: 10.1149/2.003401eel
2013-05-30In Situ Potential Distribution Measurement in an All-Vanadium Flow BatteryLiu, Q., Turhan, A.,Zawodzinski, T.,Mench, M.Chem. Commun.
2013, 49, 6292-6294
DOI: 10.1039/C3CC42092B
2013-05-24Intrinsic Thermodynamic and Kinetic Properties of Sb Electrodes for Li-ion and Na-ion Batteries: Experiment and TheoryL. Baggetto, P. Ganesh, C. Sun, R. Meisner,T. Zawodzinski, G. VeithJ. Mater. Chem. A
2013, 1, 7985-7994
DOI: 10.1039/C3TA11568B
2013-04-08Nanometer-scale Mapping of Irreversible Electrochemical Nucleation Processes on Solid Li-ion ElectrolytesA. Kumar, T. Arruda, A. Tselev, I. Ivanov, J. Lawton, T. Zawodzinski, O. Butyaev, S. Zayats, S. Jesse, S. KalininScientific Reports
3, 1621 (2013)
DOI: 10.1038/srep01621
2013-02-22Concentration Dependence of VO2+ Crossover of Nafion for Vanadium Redox Flow BatteriesLawton, J., Jones, A., Zawodzinski, T.J. Electrochem. Soc.
160 A697
DOI: 10.1149/2.004306jes
2013-02-15Probing Electrode Losses in All-Vanadium Redox Flow Batteries with Impedance SpectroscopySun, C., Delnick, F., Aaron, D., Papandrew, A., Mench, M., Zawodzinski, Jr., T.ECS Electrochem. Lett.
2 A43
DOI: 10.1149/2.001305eel
2013-02-01Qualitative Behavior of Vanadium Ions in Nafion Membranes Using Electron Spin ResonanceLawton, J., Aaron, D.,Tang, Z.,Zawodzinski, T.Journal of Membrane Sciences
428 (2013) 38-45
DOI: 10.1016/j.memsci.2012.11.003
2013-01-08In Situ Kinetics Studies in All-Vanadium Redox Flow BatteriesAaron, D., Sun, C., Bright, M., Papandrew, A., Mench, M., Zawodzinski, T.ECS Electrochem. Lett.
2 A29
DOI: 10.1149/2.001303eel
2012-07-20High Performance Vanadium Redox Flow Batteries with Optimized Electrode Configuration and Membrane SelectionLiu, Q., Grim, G.,Papandrew, A.,Turhan, A.,Zawodzinski, T.,Mench, M.J. Electrochem. Soc.
159 A1246
DOI: 10.1149/2.051208jes
2012-07-20Capital Cost Sensitivity Analysis of an All-Vanadium Redox-Flow BatteryZhang, M., Moore, M., Watson, J., Zawodzinski, T., Counce, R.J. Electrochem. Soc.
159 A1183
DOI: 10.1149/2.041208jes
2012-05-15Dramatic Performance Gains in Vanadium Redox Flow Batteries through Modified Cell ArchitectureAaron, D., Liu, Q.,Tang, Z.,Grim, G.,Papandrew, A.,Turhan, A.,Zawodzinski, T.,Mench, M.J. Power Sources
Vol. 206 (2012), pp. 450-453
DOI: 10.1016/j.jpowsour.2011.12.026
2011-08-18Polarization Curve Analysis of All-Vanadium Redox Flow BatteriesD. Aaron, Z. Tang, A. Papandrew, T. ZawodzinskiAppl Electrochem
41, 1175 (2011)
DOI: 10.1007/s10800-011-0335-7

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