That water expands when boiled, rattling pot tops on stoves, is no secret. But that it can be compressed is foreign to our daily experience.
Nevertheless, an accurate estimate of water’s shrinking volume under the huge gravitational pressures of large planets is essential to astrophysicists trying to model the evolution of the universe. They need to assume how much space is taken up by water trapped under high density and pressure, deep inside a planet, to calculate how much is needed of other elements to flesh out the planet’s astronomical image.
Overstating water’s compressibility
In a challenge to current astrophysical models, researchers at Sandia and the University of Rostock in Germany have found that current calibrations of planetary interiors overstate water’s compressibility by as much as 30 percent. The work was reported in the paper "Probing the Interior of the Ice Giants" in the Feb. 27 Physical Review Letters.
"Our results question science’s understanding of the internal structure of these planets," says lead researcher Marcus Knudson (01646), "and should require revisiting essentially all the modeling of ice giants within and outside our solar system."
To come up with the composition of the so-called ice-giants Neptune and Uranus, as well as any of the ice-giant exoplanets being discovered in distant star systems, astrophysicists begin with the orbit, age, radius, and mass of each planet. Then, using equations that describe the behavior of elements as the forming planet cooled, they calculate what light and heavy elements might have contributed in its evolution to end up with the current celestial object.
But if estimates of the volume of water are off-target, then so is everything else.
The measurements — 10 times more accurate than any previously reported — at Sandia’s Z accelerator agree with results from a modern simulation effort that uses the quantum mechanics of Schrödinger’s wave equation — the fundamental equation of wave mechanics — to predict the behavior of water under extreme pressure and density.
The model, developed through a University of Rostock and Sandia collaboration, is called "First Principles Modeling" because it contains no tuning parameters.
"You’re solving Schrödinger’s equation from a quantum mechanical perspective with hydrogen and oxygen as input; there aren’t any knobs for finagling the result you want or expect," says Marcus.
The model’s results are quite different from earlier chemical pictures of water’s behavior under pressure, but agree quite well with the Z machine’s test results, says Marcus.
These results were achieved by using Z’s magnetic fields to shoot tiny plates 40 times faster than a rifle bullet into a water sample target a few millimeters away. The impact of each plate into the target created a huge shock wave that compressed the water to roughly one-fourth its original volume, momentarily creating conditions similar to those in the interior of the ice giants.
A direct test of First Principles model
Sub-nanosecond observations captured the behavior of water under pressures and densities that occur somewhere between the surface and core of ice giants.
“We took advantage of recent, more precise methods to measure the speed of the shock wave moving through the water sample by measuring the Doppler shift of laser light reflected from the moving shock front, to 0.1 percent accuracy,” says Marcus.
The re-shocked state of water was also determined by observing its behavior as the shock wave reflected back into the water from a quartz rear window (its characteristics also determined) in the target. These results provided a direct test of the First Principles model along a thermodynamic path that mimics the path one would follow if one could bore deep into a planet’s interior.
Multiple experiments were performed, providing a series of results at increasing pressures to create an accurate equation of state. Such equations link changes in pressure with changes in temperatures and volumes.
Z can create more pressure— up to 20 megabars— even than at Earth’s core (about 3.5 megabars) and millions of times Earth’s atmospheric pressure. The Z projectiles, called flyer plates, achieve velocities from 12 to 27 kilometers a second, or up to 60,000 mph. The pressure at the center of Neptune is roughly 8 megabars.
Water at Z’s ice-giant pressures also was found to have reflectivity indicative of a weak metal, raising the possibility that water’s charged molecular fragments might be capable of generating a magnetic field. This attribute could help explain certain puzzling aspects of the magnetic fields around Neptune and Uranus.
"Reducing uncertainty on the composition of planetary systems by precisely measuring the equation of state of water at extreme conditions can only help us understand how these systems formed," says Marcus.
These techniques also are used to study materials of critical importance to the nuclear weapons program.
In addition to producing the largest amount of laboratory X-rays on Earth when firing, the huge pressures generated by Z make it useful to astrophysicists seeking data similar to that produced by black holes and neutron stars .
Also listed as paper authors are Mike Desjarlais (1640), Ray Lemke (1641), and Thomas Mattsson (1641) from Sandia, and Martin French, Nadine Nettelmann, and Ronald Redmer from the University of Rostock’s Institute of Physics. Research support was provided by the German Science Foundation and NNSA.