Sandia National Laboratories
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Eric G. Sorte and Todd M. Alam TM, “1H-19F REDOR-Filtered NMR Spin Diffusion Measurements of Domain Size in Heterogeneous Polymers” Magn. Reson. Chem., 1–9 (2017).

Brad H. Jones, David R. Wheeler, Hayden T. Black, Mark E. Stavig, Patricia S. Sawyer, Nicholas H. Giron, Mathias C. Celina, Timothy N. Lambert, and Todd M. Alam, “Stress Relaxation in Epoxy Thermosets via a Ferrocene-Based Amine Curing Agent”, Macromolecules, 50(13), 5014-5024 (2017) DOI: 10.1021/acs.macromol.7b00501

Frederick G. Baddour, Ariel S. Hyre, Jesse L. Guillet, David Pascual, José Maria Lopez-de-Luzuriaga, Todd M. Alam, Jeffrey W. Bacon, and Linda H. Doerrer, “Pt–Mg, Pt–Ca, and Pt–Zn Lantern Complexes and Metal-Only Donor–Acceptor Interactions”, Inorganic Chemistry,56(1) 452-469(2016), DOI: 10.1021/acs.inorgchem.6b02372

Kyoungtae Kim, Todd M. Alam, Joseph D. Lichtenhan, Joshua U. Otaigbe, “Synthesis and Characterization of Novel Phosphate Glass Matrix Nanocomposites Containing Polyhedral Oligomeric Silsesquioxane with Improved Properties”, J. Non-Crystalline Solids, 463, 189-202 (2017).


Todd M. Alam, Mark K. Kinnan,Brendan W. Wilson, and David R. Wheeler, “Sub-Equimolar Hydrolysis and Condensation of Organophosphates”,  Chemistry Select, 1, 2698-2705 (2016). DOI:

Todd M. Alam and Thomas M. Osborn Popp, “In-Pore Exchange and Difffusion of Carbonate Solvent Mixture in Nanoporous Carbon” Chem. Phys. Lett., 658, 51-57 (2016). doi:10.1016/j.cplett.2016.06.014

Todd M. Alam, Zuolei Liao, May Nyman and Jonathan Yates, “Insight into Hydrogen Bonding of Uranyl Hydroxide Layers and Capsules by Use of 1H Magic-Angle Spinning NMR Spectroscopy”, J. Phys. Chem. C, 120(19), 10675-10685 (2016) DOI: 10.1021/acs.jpcc.6b02692

Timothy J. Boyle, Jeremiah M. Sears, Michael L. Neville, Todd M. Alam, Victor G, Young, “Structural Properties of the Acidification Products of Scandium Hydroxy Chloride Hydrate”,  Inorganic Chemistry, 54(24), 11831-11841 (2016), DOI: 10.1021/acs.inorgchem.5b02030

Maryam K. Mardke, Baiyu Huang, Calvin H. Bartholomev, Todd M. Alam, Brian F. Woodfield, “Synthesis and Characterization of Silica Doped Alumina Catalyst Support with Superior Thermal Stability and Unique Pore Properties”, Journal Porous Materials, 23(2), 475-487 (2016).
 DOI: 10.1007/s10934-015-0101-z

Timothy J. Boyle, Michael L. Neville, Jeremiah M. Sears, Roger E. Cramer, Mark A. Rodriguez, Todd M. Alam, Samuel P. Bingham, “ Synthesis, X-​ray Structures, and Characterization of Hexafluoro-​iso-​propoxide Group 3 and Lanthanide Precursors”, Polyhedron, 118, 52-60 (2016).


Brad H. Jones, David R. Wheeler, Jill S. Wheeler, Lance L. Miller, Todd M. Alam, and Erik D. Spoerke, “Isomer-Sensitive Deboronation in Reductive Aminations of Aryl Boronic Acids”, Tetrahedron Letters, 56, 5731-5734 (2015). DOI:10.1016/j.tetlet.2015.09.006

Timothy J. Boyle, Michael L. Neville, Daniel T. Yonemoto, Todd M. Alam, Lily Jan, “Coordination Chemistry of 2,6-Dimethanol Pyridine with Early Transition Metal Alkoxide Compounds”, J. Coordination Chemistry, 68(9), 1616-1632 (2015). DOI:10.1080/00958972.2015.1028382

Todd M. Alam and Nelson Bell and Jill Wheeler and Erik D. Spoerke and Randall T. Cygan and David Ingersoll, “Exploring the Role of Phosphate Structural Distortions on the Sodium Jump Dynamics in NASICON Phases”, MRS Online Proceedings, 1773 (2015) mrss15-2126591, 

Catherine FM Clewett1, Todd M Alam, Eric S Osantowski and Michael J Pullin, “Structural Characterization of Humic Materials Using 13C Nuclear Magnetic Resonance Techniques: A Comparison of Solution and Solid-State Methods”, J. Environ. Anal. Chem., 2,121. doi: 10.4172/JREAC.1000121

Todd M. Alam, C. J. Pearce, "Infrared Signature of Micro-Hydration in the Organophosphate Sarin: an Ab Initio Study", Journal Molecular Modeling, 21(7), 1-8 (2015). doi: 10.1007/s00894-015-2732-z

Timothy J. Boyle, Michael L. Neville, Daniel T. Yonemoto, Todd M. Alam, Lily Jan, “Coordination Chemistry of 2,6-Dimethanol Pyridine with Early Transition Metal Alkoxide Compounds”, J. Coordination Chemistry, 68(9), 1616-1632 (2015). DOI:10.1080/00958972.2015.1028382

Brad H. Jones, David R. Wheeler, Jill S. Wheeler, Lance L. Miller, Todd M. Alam, and Erik D. Spoerke, “Isomer-Sensitive Deboronation in Reductive Aminations of Aryl Boronic Acids”, Tetrahedron Letters, 56, 5731-5734 (2015). doi:10.1016/j.tetlet.2015.09.006


Rebecca E. Olsen, Todd M. Alam, Calvin H. Bartholomew, David B. Enfield, Jacob Schliesser, Brian F. Woodfield, “Structure Analysis of Al-Modified TiO2; Nano Catalyst Supports”, J. Phys. Chem. C, 118(17), 9176-9186 (2014).

Todd M. Alam, Zuolei Liao, Lev N. Zacharov, May Nyman, “Solid-State Dynamics of Uranyl Polyoxometalates”, Chemistry, A. Eur. J., 20(27), 8302-8307 (2014).  

Maryam Khosravi Mardkhe, Kamyar Keyvanloo, Calvin H. Bartholomew, William C. Hecker, Todd M. Alam, Brian F. Woodfield, “Acid Site Properties of Thermally Stable, Silica-Doped Alumina as a Function of Silica/Alumina Ratio and Calcination Temperature”,  Applied Catalysis A: General, 482, 16-23 (2014).

Todd M. Alam, Kimberly K. Childress, Kevin Pastoor, Charles V. Rice, “Characterization of Free, Restricted and Entrapped Water Environments in Poly(N-Isopropyl Acrylamide) Hydrogels via 1H HRMAS PFG NMR Spectroscopy”, J. Polymer Science: Polymer Physics, 52 1521-1527 (2014)

Todd M. Alam and Michael R. Hibbs, “Characterization of Heterogeneous Solvent Diffusion Environments in Anion Exchange Membranes”, Macromolecules, 47, 1073-1084 (2014).

Kamyar Keyvanloo, Maryam Khosravi Mardkhe, Todd M. Alam, Calvin H. Bartholomew, Brian F. Woodfield, and William C. Hecker, “Supported Iron Fischer–Tropsch Catalyst: Superior Activity and Stability Using a Thermally Stable Silica-Doped Alumina Support”, ACS Catal., 4, 1071-1077 (2014).

Todd M. Alam and Charels J. Pearce, "Impact of Graphene Incorporation on the Orientational Order of Graphene/Liquid Crystal Composites", Chem. Phys. Lett., 592, 7-13 (2014).


C. Francisco Buitrago, Janelle E. Jenkins, Kathleen L. Opper, Brian S. Aitken, Kenneth B. Wagener, Todd M. Alam, and Karen I. Winey, “Room Temperature Morphologies of Precise Acid- and Ion-Containing Polyethylenes”, Macromolecules, 46(22), 9003-9012 (2013). http:/dx/

C. Francisco Buitrago, Todd M. Alam, Kathleen L. Opper, Brian S. Aitken, Kenneth B. Wagener, and Karen I. Winey, “Morphological Trends in Precise Acid- and Ion-Containing Polyethylenes at Elevated Temperature”, Macromolecules, 46(22),8995-9002 (2013). http:/dx/

Todd M. Alam, “Ab Initio Calculations of Possible γ-Gauche Effects in the ,13C-NMR for Methine and Carbonyl Carbons in Precise Polyethylene Acrylic Copolymers”, Molecules, 18(8), 9010-9020.

Timothy J. Bolye, Andrew T. Velazquez, Daniel T. Yonemoto, Todd M. Alam, Curtis Moore, Arnold L. Rheingold, “Synthesis and Characterization of a Family of Solvated Sodium Aryloxide Compounds”, Inorganica Chimia Acta,  405, 374-386 (2013).

Todd M. Alam, Daniel R. Dreyer, Christopher W. Bielawski, and Rodney S. Ruoff, “Combined Measurement of Translational and Rotational Diffusion in Quantenary Acyclic Ammonium and Cyclic Pyrrolidinium Ionic Liquids”, J. Phys. Chem. B, 117, 1967-1977 (2013).


Todd M. Alam, Janelle E. Jenkins, Dan S. Bolinitineanu, Mark J. Stevens, Amalie L. Frischknecht, C. Francisco Buitrago, Karen I. Winey, Kathleen L. Opper and Kenneth B. Wagener, “Heterogeneous Coordination Environments in Lithium-Neutralized Ionomers Identified Using 1H and 7Li MAS NMR”, Materials,  5, 1508-1527 (2012).

May Nyman and Todd M. Alam, “Dynamics of Uranyl Peroxide Nanocapsules”, J. Am. Chem. Soc., 134, 20131-20138 (2012).

Vitalie Stavila, Raghunandan K. Bhakta, Todd M. Alam, Eric H. Majzoub, and Mark D. Allendorf, “Reversible Hydrogen Storage by NaAlH4 Confined Within a Titanium-Functionalized MOF-74(Mg) Nanoreactor”, ACS NANO,6(11), 9807-9817 (2012). Paper

Todd M. Alam and Janelle E. Jenkins, “ HR-MAS NMR Spectroscopy in Material Science”, in Advanced Aspects of Spectroscopy, Muhammad Akhyar Farrukh (Ed.), ISBN: 978-953-51-0715-6, InTech, (2012) Chapter Available:

Todd M. Alam, Muniasamy Neerathilingam, M. Kathleen Alam, David E. Volk, G. A. Shakeel Ansar, Swapna Sarkar and Bruce A Luxon, “1H Nuclear Magnetic Resonance (NMR) Metabolomic Study of Chronic Organophosphate Exposure in Rats”, Metabolites, 2(3), 479-495 (2012). paper

Yu Hou, Todd M. Alam, Mark A. Rodriguez, May Nyman, “Aqueous Compatibility of Group IIIA Monomers and Nb-Polyoxoanions”, ChemComm, 48, 6004-6006 (2012). paper

Janelle E. Jenkins, Michelle E. Seitz, C. Francisco Buitrago, Karen I. Winey, Kathleen L. Opper, Travis W. Baughman, Kenneth B. Wagener and Todd M. Alam, “The Impact of Zinc Neutralization on the Structure and Dynamics of Precise Polyethylene Acrylic Acid Ionomers: A Solid-State 13C NMR Study”, Polymer, 53, 3917-3927, (2012). paper

Todd M. Alam, C.J. Pearce and Janelle Jenkins, “Ab Initio Investigation of Sarin Micro-Hydration”, Computational and Theoretical Chemistry, 995, 24-35, (2012). paper

Janelle J. Jenkins, Michael R. Hibbs and Todd M. Alam, “Identification of Multiple Diffusion Rates in Mixed Solvent Anion Exchange Membranes Using High Resolution MAS NMR”, ACS Macro Letters, 1, 910-914 (2012).paper

Raghunandan K. Bhakta, Sean Maharrey, Vitalie Stavila, Aaron Highley, Todd M. Alam, Eric Majzoub, and Mark Allendorf, “Thermodynamics and Kinetics of NaAlH4 Nanocluster Decomposition”, Phys. Chem. Chem. Phys.,14, 8160-8169 (2012). paper


Timothy J. Boyle, Leigh Anna M. Steele, Alia M. Saad, Mark A. Rodriguez, Todd M. Alam and Sarah K. McIntyre, Structural Diversity in a Series of Alkyl-Substituted Cesium Aryloxides”, Inorganic Chemistry, 50, 10363-10370 (2011). paper

Jeffery Potts, Sun Lee, Jinho An, Meryl Stoller, Richard Piner, Todd M. Alam, Rodney Ruoff, “Thermomechanical Properties of Poly(methyl Methacrylate)/Chemically Modified Graphene Nanocomposites Made by In Situ Polymerization”, Carbon, 49(8), 2615-2623 (2011). paper

Todd M. Alam, Janelle E. Jenkins,  Michelle E. Seitz,  C. Francisco Buitrago, Karen I. Winey, Kathleen L. Opper, Travis W. Baughman and Kenneth B. Wagener “ 1H MAS NMR Spectroscopy of Polyethylene Acrylic Acid Copolymers and Ionomers”, Chapter 7 in NMR Spectroscopy of Polymers: Innovative Stratigies for Complex Macromolecules; edited by H. Cheng et al., 115-131 (2011).

Jenkins, Janelle E.; Seitz, Michelle E.; Buitrago, C. Francisco; Winey, Karen I.; Opper, Kathleen L.; Baughman, Travis W.; Wagener, Kenneth B.; Todd M. Alam, “Random or precise? Solid-state NMR structure and dynamics characterization of zinc neutralized polyethylene acrylic acid ionomer”,  ACS Polymer Preprints, 52(2), 332-333 (2011).

T. M. Alam, D. Hart, S. L. B. Rempe, "Computing the 7Li NMR Chemical Shielding of Hydrated Li+ using Cluster Calculations and Time-Averaged Configurations from ab initio Molecular Dynamics Simulations", Physical Chemistry Chemical Physics, 13, 13629-13637, (2011). paper

J. C. Harper, D. M. Lopez, E. C. Larkin, M. K. Economides, S. K. McIntyre, T. M. Alam, M. S. Tartis, M. Werner-Washburne, C. J. Brinker, S. M. Brozik, D. R. Wheeler, "Encapsulation of S. cerevisiae in Poly(glycerol) Silicate Derived Matrices: Effect of Matrix Additives and Cell Metabolic Phase on Long-Term Viability and Rate of Gene Expression", Chemistry of Materials, 23 (10), 2555-2564, (2011). paper

J. W. Blanchard, J. P. Belieres, T. M. Alam, J. L. Yarger, G. P. Holland, "NMR Determination of the Diffusion Mechanisms in Triethylamine-Based Protic Ionic Liquids", Journal of Physical Chemistry Letters, 2 (9), 1077-1081 (2011). paper

M. Nyman, M. A. Rodriguez, T. M. Alam, "The U28 nanosphere: what's inside?", European Journal of Inorganic Chemistry, 14, 2197-2205, (2011). paper

T. M. Alam, D.R. Dreyer, C. W. Bielwaski, R. S. Ruoff, "Measuring Molecular Dynamics and Activation Energies for Quaternary Acyclic Ammonium and Cyclic Pyrrolidinium Ionic Liquids using 14N NMR Spectroscopy", The Journal of Physical Chemistry A, 115 (17), 4307-4316 (2011). paper


J. S. Clawson, R. T. Cygan, T. M. Alam, K. Leung, S. B. Rempe, "Ab initio study of hydrogen storage in water clathrates", Journal of Computational and Theoretical Nanoscience, 7, 2602-2606 (2010). paper

M. Nyman, T. M. Alam, S. K. McIntyre, G. C. Bleier, D. Ingersoll, "Alternative Approach to Increasing Li Mobility in Li-La-Nb/Ta Garnet Electrolytes", Chemistry of Materials, 22, 5401-5410 (2010). paper

T. N. Lambert, C.C. Luhrs, C. A. Chavez, S. Wakeland, M. T. Brumbach, T. M. Alam, "Graphite Oxide as a Precursor for the Synthesis of Disordered Graphenes Using the Aerosol-Through-Plasma Method", Carbon, 48, 4081-4089 (2010). paper

M. Neerathilingam, D. E. Volk, S. Sarkar, T. M. Alam, M. K. Alam, G. A. Shakeel Ansari, B. A. Luxon, "1H NMR-Based Metabonomic Investigation of Tributyl Phosphate Exposure in Rats", Toxicology Letters, 199, 10-16 (2010). paper

A. L. Costello, T. M. Alam, "Investigating the Impact of Cholesterol on Magnetically Aligned Sphingomyelin/Cholesterol Multilamellar Vesicles Using 31P NMR", Chemistry and Physics of Lipids, 163, 506-513 (2010). paper

T. M. Alam, M. K. Alam, M. Neerathilingam, D. E. Volk, S. Sarkar, G. A. Shakeel Ansari, B. A. Luxon, "1H NMR Metabonomic Study of Rat Response to Tri-Phenyl Phosphate and tri-Butyl Phosphate Exposure", Metabolomics, 6, 386-394 (2010). paper

M. T. Brumbach, T. M. Alam, P. G. Kotula, B. B. McKenzie, B. C. Bunker, "Nanostructured ruthenium oxide electrodes via high-temperature molecular templating for use in electrochemical capacitors," ACS Applied Materials & Interfaces, 2, 778-787 (2010). paper

T. J. Boyle, L. A. M. Ottley, T. M. Alam, M. A. Rodriguez, P. Yang, S. K. McIntyre, "Structural characterization of methanol substituted lanthanum halides," Polyhedron, 29, 1784-1795 (2010). paper

T. M. Alam, M. K. Alam, "Development of variance-filtered instrumental transfer methods for high-resolution NMR spectroscopy," Journal of Chemometrics (2010). paper


T. J. Boyle, H. P. Pratt III, L. A. M. Ottley, T. M. Alam, S. K. McIntyre, M. A. Rodriguez, J. Farrell, C. F. Campana, "Homo- and heterometallic complexes of tetra-(di-substituted hydroxybenzyl)-N,N'-ethylenediamine derivatives," Inorganic Chemistry, 48, 9191-9204 (2009). paper

M. A. Hickner, G. J. Tudryn, T. M. Alam, M. R. Hibbs, C. H. Fujimoto, "Polymers with tethered anionic and cationic groups as membranes for fuel cells," Macromolecular Symposia, 279 (Polymers at Frontiers of Science and Technology -- MACRO 2008), 59-62 (2009).

D. R. Dunphy, T. M. Alam, M. P. Tate, H. W. Hillhouse, B. Smarsly, A. D. Collord, E. Carnes, H. K. Baca, R. Kohn, M. Sprung, J. Wang, C. J. Brinker, "Characterization of Lipid-Templated Silica and Hybrid Thin Film Mesophases by Grazing Incidence Small-Angle X-ray Scattering," Langmuir, 25, 9500-9509 (2009). paper

C. J. Orendorff, T. M. Alam, D. Y. Sasaki, B. C. Bunker, J. A. Voigt, "Phospholipid-Gold Nanorod Composites," ACS Nano, 3, 971-983 (2009). paper

T. J. Boyle, H. D. Pratt, T. M. Alam, T. Headley, M. A. Rodriguez, "Synthesis and characterization of thiolate-oxo ligated zinc alkyl derivatives for production of Zn-based nanoparticles," European Journal of Inorganic Chemistry, 7, 855-865 (2009). paper

T. A. Stewart, D. E. Trudell, T. M. Alam, C. A. Ohlin, C. Lawler, W. H. Casey, S. Jett, M. Nyman, "Enhanced Water Purification: A Single Atom Makes a Difference," Environmental Science and Technology, 43, 5416-5422 (2009). paper

T. M. Alam, M. K. Alam, S. K. McIntyre, D. Volk, M. Neerathilingam, B. A. Luxon, "Investigation of Chemometric Instrumental Transfer Methods for High Resolution NMR Data Sets," Analytical Chemistry, 81, 4433-4443 (2009). paper

M. Nyman, T. M. Anderson, T. M. Alam, A. Ambrosini, "Aqueous Synthesis and Structural Comparison of Rare Earth Niobates and Tantalates: (La,K,#)2Nb2O7-x(OH)2 and Ln2Ta2O7(OH)2 (# = vacancy; Ln = La-Sm)," Chemistry of Materials, 21, 2201-2208 (2009). paper


A. L. Costello, T. M. Alam, "Using 31P MAS NMR to Monitor a Gel Phase Thermal Disorder Transition in Sphingomyelin/Cholesterol Bilayers,” Biochimica Biophysica Acta, 1778, 97-104 (2008). paper

T. M. Alam, J. S. Clawson, F. Bonhomme, S. G. Thoma, M. A. Rodriguez, S. Zheng, J. Autschbach, “A Solid State NMR, X-ray Diffraction and Ab Initio Investigation into the Structures of Novel Tantalum Oxyfluoride Clusters,”Chemistry of Materials, 20, 2205-2217 (2008). paper

T. M. Alam, S. K. McIntyre, C. H. Fujimoto, M. R. Hibbs, M. A. Hickner, “Pulse Field Gradient NMR Investigation of Water Diffusion in Proton and Anion Exchange Membranes,” Polymer Preprints (American Chemical Society, Division of Polymer Chemistry), 49(1), 718-719 (2008).

M. R. Hibbs, M. A. Hickner, T. M. Alam, S. K. McIntyre, C. H. Fujimoto, C. J. Cornelius, “Transport Properties of Hydroxide and Proton Conducting Membranes,”Chemistry of Materials, 20(7), 2566-2573 (2008). paper

M. Nyman, C. R. Powers, F. Bonhomme, T. M. Alam, E. J. Maginn, D. T. Hobbs, “Ion-Exchange Behavior of One-Dimensional Linked Dodecaniobate Keggin Ion Materials,” Chemistry of Materials, 20(7), 2513-2521 (2008). paper

T. M. Alam, S. K. McIntyre, “Self-Assembly and Magnetic Alignment in Cetyltrimethylammonium Bromide/Sodium Perfluorooctanoate Surfactant Mixtures Investigated Using 2H Nuclear Magnetic Resonance Spectroscopy,” Langmuir, 24(24), 13890-13896 (2008). paper

T. J. Boyle, L. A. M. Ottley, M. A. Rodriguez, R. M. Sewell, T. M. Alam, S. K. McIntyre, “Stepwise Modification of Titanium Alkoxy Chloride Compounds by Pyridine Carbinal,” Inorganic Chemistry, 47(22), 10708-10717 (2008). paper

T. M. Anderson, T. M. Alam, M. A. Rodriguez, J. N. Bixler, W. Xu, J. B. Praise, M. D.Nyman, “Cupric Siliconiobate. Synthesis and Solid State Studies of a Pseudosandwich-Type Heteropolyanion,” Inorganic Chemistry, 47(17), 7834-7839 (2008). paper

S. A. Madbouly, T. M. Alam, J. U. Otaigbe, “Viscoelasticity and Crystallization of PC/mPP Nanoblends Prepared via in Situ Polymerization and Compatiblization,” AIP Conference Proceedings, 1027(Pt. 2, 15th International Congress on Rheology, 2008), 887-889 (2008).

G. P. Holland, T. M. Alam, “Unique Backbone-Water Interaction Detected in Sphingomyelin Bilayers with 1H/31P and 1H/13C HETCOR MAS NMR spectroscopy,” Biophysical Journal, 95(3), 1189-1198 (2008). paper

R. T. Cygan, T. M. Alam, C. J. Brinker, B. C. Bunker, J. S. Clawson, L. J. Criscenti, P. S. Crozier, D. Farrow, P. J. Feibelman, B. L. Frankamp, G. P. Holland, J. E. Houston, D. L. Huber, Y.-B. Jiang, K. Leung, C. D. Lorenz, T. M. Nenoff, M. D. Nyman, N. W. Ockwig, C. J. Orendorff, J. D. Pless, S. B. Rempe, S. Singh, M. J. Stevens, K. Thuermer, F. B. van Swol, S. Varma, R. C. Major, M. J. McGrath, J. I. Siepmann, X. Zhu, J. L. Cecchi, Z. Chen, D. R. Dunphy, H. Gerung, D. J. Kissel, N. Liu, G. K. Xomeritakis, J. A. Anderson, A. Travesset, L. L. Daemen, M. A. Hartl, and H. Xu ,"Exploiting Interfacial Water Properties for Desalination and Purification Applications" SAND Report SAND2008-5729 (2008). paper


S. K. McIntyre, T. M. Alam, "17O NMR Investigation of Phosphite Hydrolysis Mechanisms," Magnetic Resonance in Chemistry, 45, 1022-1026 (2007). paper

T. M. Nenoff, N. W. Ockwig, T. M. Alam, M. Hartl, L. L. Daemen, “The Role of Water in Zeolite Pores: The Structure/Property Relationship for Ion Exchange”, In Studies in Surface Science and Catalysis, 170A, Eds. R. Xu, J. Chen, Z. Gao, W. Yan, 790-795 (2007). book info

T. J. Boyle , H. D. Pratt III, T. M. Alam, M. A. Rodriguez, P. G. Clem, "Synthesis and characterization of solvated trifluoroacetate alkaline earth derivatives," Polyhedron, 26, 5095–5103 (2007). paper

T. M. Anderson, M. A. Rodriguez, F. Bonhomme, J. N. Bixler, T. M. Alam, M. Nyman, "An aqueous route to [Ta6O19]8– and solid-state studies of isostructural niobium and tantalum oxide complexes," Dalton Transactions, 40, 4517-4522 (2007). paper Check out the cover! Way to go, May!

T. M. Nenoff, N. W. Ockwig, R. T. Cygan, T. M. Alam, K. Leung, J. D. Pless, H. Xu, M. A. Hartl, L. L. Daemen, "Role of water in the ion selectivity of niobate-based octahedral molecular sieves," Journal of Physical Chemistry C, (2007). paper

T. J. Boyle, L. A. M. Ottley, S. D. Daniel-Taylor, L. J. Tribby, S. D. Bunge, A. L. Costello, T. M. Alam, J. C. Gordon, T. M. McCleskey, “Isostructural neo-pentoxide derivatives of group 3 and the lanthanide series metals for the production of Ln(2)O(3) nanoparticles,” Inorganic Chemistry, 46, 3705-3713 (2007). paper

T. M. Alam, M. Nyman, S. K. McIntyre, “Double quantum 1H MAS NMR studies of hydrogen-bonded protons and water dynamics in materials,” Journal of Physical Chemistry B, 111, 1792-1799 (2007). paper

T. M. Anderson, S. G. Thoma, F. Bonhomme, M. A. Rodriguez, H. Park, J. B. Parise, T. M. Alam, J. P. Larentzos, M. Nyman, “Lithium polyniobates. A lindqvist-supported lithium-water adamantine cluster and conversion of hexaniobate to a discrete keggin complex,” Crystal Growth and Design, 7, 719-723 (2007). paper


M. Nyman, A. J. Celestian, J. B. Parise, G. P. Holland, T. M. Alam, “Solid-state structural characterization of a rigid framework of lacunary heteropolyniobates,” Inorganic Chemistry, 45, 1043-1052 (2006). paper

L. O. Sillerud, A. F. McDowell, N. L. Adolphi, R. E. Serda, D. P. Adams, M. J. Vasile, T. M. Alam, “1H NMR detection of superparamagnetic nanoparticles at 1T using a microcoil and novel tuning circuit,” Journal of Magnetic Resonance, 181, 181-190 (2006). paper

T. M. Alam and G. P. Holland, “1H-13C INEPT MAS NMR Correlation Experiments with 1H-1H Mediated Magnetization Exchange to Probe Organization in Lipid Biomembranes”, Journal of Magnetic Resonance, 180, 210-221 (2006). paper

G. P. Holland, S. K. McIntyre, and T. M. Alam, “Distinguishing Individual Lipid Headgroup Mobility and Phase Transitions in Raft Forming Lipid Mixtures with 31P MAS NMR”, Biophysical Journal, 90, 4248-4260 (2006). paper

G. P. Holland and T. M. Alam, “Multi-Dimensional 1H-13C HETCOR and FSLG-HETCOR NMR Study of Sphingomyelin Bilayers Containing Cholesterol in the Gel and Liquid Crystalline States”, Journal of Magnetic Resonance, 181, 316-326 (2006). paper

J. S. Clawson, G. P. Holland and T. M. Alam, “Magnetic Alignment of Aqueous CTAB in Nematic and Hexagonal Liquid Crystalline Phases Investigated by Spin-1 NMR”, Physical Chemistry Chemical Physics, 8, 2636-2641 (2006). paper

M. Nyman, T. M. Alam, F.  Bonhomme, M. A. Rodriguez, C. S. Frazer and M. E. Welk , “Solid-state Structures and Solution Behavior of Alkali Salts of the [Nb6O18]8- Lindqvist Ion”, Journal of Cluster Science, 17, 197-219 (2006). paper

M. V. Childress, D. Millar, T. M. Alam, K. A. Kreisel, G. P. A. Yap, L. N. Zakharov, J. A. Golen, A. L. Rheingold, L. H. Doerrer, “Thallophillic Interactions in Aryloxide Compounds: the {Tl22-OAr)4} Structural Motif in (TlOAr)4 and Tl2Cu(OAr)4 Compounds”, Inorganic Chemistry, 45, 3864-3877 (2006). paper


T. M. Alam, B. R. Cherry, K. R. Minard, M. Celina, “Relaxation Nuclear Magnetic Resonance Imaging of Heterogeneous Aging in a Hydroxy-Terminated Polybutadiene Based Elastomer”, Macromolecules, 38, 10694-10701. paper

T. M. Alam, J. U. Otaigbe, D. Rhoades, G. P. Holland, B. R. Cherry and P. G. Kotula, “Nanostructure Polymer Blends: Synthesis and Structure”,  Polymer, 46(26), 12468-12479 (2005). paper

T. M. Alam, B. C. Tischendorf, R. K. Brow, “High Speed 1H MAS NMR Investigations of the Weathered Surface of a Phosphate Glass”, Solid State Nuclear Magnetic Resonance, 27(1-2), 99-111 (2005). paper

T. M. Alam and M. K. Alam, “Chemometric Analysis of NMR Spectroscopy Data: A Review”, Annual Reports on NMR Spectroscopy, 54, 41-80 (2005). paper

B. R. Cherry, C. H. Fujimoto, C. J. Cornelius, T. M. Alam, “Investigation of Domain Size in Polymer Membranes Using Double-Quantum-Filtered Spin Diffusion Magic Angle Spinning NMR”, Macromolecules, 38, 1201-1206 (2005). paper

F. Bonhomme, J. P. Larentzos, T. M. Alam, E. J. Maginn, M. Nyman, “Synthesis, Structural Characterization, and Molecular Modeling of Dodecaniobate Keggin Chain Materials”, Inorganic Chemistry, 44, 1774-1785 (2005). paper

G. P. Holland and T. M. Alam, “Location and Orientation of Adsorbed Molecules in Zeolites From Solid-State REAPDOR NMR”, Phys. Chem. Chem. Phys., 7, 1739-1742 (2005). paper Also check out this 2004 SAND report on zeolite-adsorbed methane!

M. Nyman, D. Ingersoll, S. Singh, F. Bonhomme, T. M. Alam, C. F. Brinker, M. A. Rodrigez, “Comparative Study of Inorganic Cluster-Surfactant Arrays”, Chem. Materials, 17, 2885-2895 (2005). paper

T. J. Boyle, L. J. Tribby, T. M. Alam, S. D. Bunge, G. P. Holland, “Catechol Derivatives of Group 4 and 5 Compounds”, Polyhedron, 24, 1143-1152 (2005). paper

T. J. Boyle, N. L. Andrews, T. M. Alam, D. R. Tallant, M. A. Rodrigez, D. Ingersol, “Speciation in the AlCl3/SO2Cl2 Catholyte System”, Inorganic Chemistry, 44(16), 5934-5940 (2005). paper

T. J. Boyle, T. M. Alam, S. D. Bunge, J. M. Segall, G. R. Avilucea, R. G. Tissot, M. A. Rodriguez, “Tetrahydrofurfuryloxide Derivatives of Alkyl Aluminum Species”, Organometallics, 24, 731-737 (2005). paper

T. J. Boyle, S. D. Bunge, T. M. Alam, G. P. Holland, T. J. Headley, G. Avilucea, “Cadmium Amido Alkoxide and Alkoxide Precursors for the Synthesis of Nanocrystalline CdE (E = S, Se, Te)," Inorganic Chemistry, 44(5), 1309-1318 (2005). paper

H. Fan, Z. Chen, J. Brinker, J. Clawson. T. M. Alam, “Synthesis of Organo-Silane Functionalized Nanocrystal Micelles and Their Self Assembly”, J. Am. Chem. Soc., 127 (40), 13746-13747 (2005). paper

T. M. Alam and G. S. Timmins, “Use of 17O in NMR and EPR Investigations of Polymer Aging: A Mini Review”, in Service Life Prediction: Challenging the Status Quo, Ed. J. W. Martin, R. A. Ryntz, R. A. Dickie, Federations of Societies for Coating Technologies, 297-303 (2005). book info

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Todd M. Alam

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last update: June 27, 2011
content owner: Todd M. Alam