| Plenary Presentations
Frontiers of Interfacial Water Research Workshop |
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| Six plenary lectures were presented during the course of the workshop to provide general topical reviews and to stimulate discussion for the breakout sessions. Researchers at the University of Illinois at Urbana-Champaign presented the first set of plenary lectures. In the opening lecture, Steve Granick provided a summary of the physics and chemistry of interfacial water with an emphasis on the "puzzles and opportunities" in spectroscopic measurements. Granick highlighted experimental measurements of the disorder state, fluidity, transport, and shear forces associated with surface and confined water. Among the analytical methods, Granick highlighted results obtained from atomic force microscopy, surface force apparatus, surface enhanced Raman spectroscopy, ellipsometry, X-ray reflectivity, and fluorescence resonance energy transfer. Jim Kirkpatrick presented the results from several environmental science projects that combine spectroscopy with molecular simulation to provide detailed atomic descriptions of the structure, energy, and transport of water on complex oxide surfaces. Sum frequency vibrational spectroscopy and magic-angle spinning NMR spectroscopy were incorporated in these efforts. Classical molecular simulation methods were used to obtain equilibrated models that describe the hydrogen bonding networks and unique behavior of the water layers as a function of distance from the interface. Narayan Aluru completed the first session with his presentation on the multiscale analysis of water and ion transport in nanochannels. Aluru used classical molecular dynamics and a modified Poisson-Boltzmann method to model density profiles for water and electrolytes within various-sized channels at different charge distributions. Embedded methods that combine molecular dynamics with a continuum approach were also used to help bridge spatial scales. Aluru emphasized the usefulness of these theoretical methods to model complex processes associated with membranes having multiple asymmetric channels, and biomimetic and hybrid channels.
Neal Sturchio of the University of Illinois at Chicago reviewed the use of several synchrotron-radiation methods to investigate the structure of interfacial water for various oxide and mineral systems. Sturchio demonstrated the effectiveness of high-resolution X-ray scattering techniques such as grazing-incidence X-ray reflectivity, surface and thin-film diffraction, crystal truncation rods, and X-ray standing waves methods. Results from synchrotron experiments involving interfacial water and quartz, rutile, muscovite, orthoclase, alumina, hematite, and other materials surfaces were presented. The plenary presentation by Michael Tsapatsis of the University of Minnesota reviewed the application of zeolite materials for water treatment. Tsapatsis reviewed the various structures and compositions of crystalline molecular sieve materials, and emphasized their utility in chemical separation, catalysis, chemical sensors, and as nanostructured hosts. The synthesis and characterization methods for these materials were discussed, and selected materials specifically for water treatment were highlighted. The final plenary presentation was given by Tony Haymet of CSIRO Marine Research in Hobart, Tasmania. Haymet emphasized the lack of understanding associated with solutes at interfaces, particularly for processes occurring at hydrophobic surfaces. Haymet reviewed several models of the ice-water interface and compared the thermodynamics of ion solvation in water and in ice. Haymet discussed experiments measuring the Workman-Reynolds effect, which is the electrical potential of liquid relative to ice generated during the freezing of dilute aqueous systems. Several biological applications involving water-ice issues were presented. These included the analysis of antifreeze proteins, associated with some fish species, simulations of the lipid bilayer, and the preservation of sheep cells upon freezing. Additional presentations were given by Neal Shinn of Sandia National Laboratories and by Mark Shannon of the University of Illinois at Urbana-Champaign. Shinn provided a general review of the role of water research at Sandia, with particular emphasis on nanoscience issues and the recent development of the Center for Integrated Nanotechnologies, which is a DOE National User Facility. Shannon introduced the workshop participants to WaterCAMPWS, Center of Advanced Materials for Purification of Water with Systems. WaterCAMPWS is sponsored by the National Science Foundation, and is a research and education center for increasing water supplies for human use through enhanced treatment technologies. | ||
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Center for Integrated Nanotechnologies, CINT |
Sandia Water Initiative
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